Plant protection agents based on pyrazolecarboxylic acid derivatives

ABSTRACT

The present invention relates to agents for protecting crop plants from the phytotoxic side effects of herbicides, which agents contain a compound of the formula I ##STR1## wherein Y denotes C--H or N, 
     the symbols R 1  independently of one another denote alkyl, halo-alkyl, alkoxy, haloalkoxy or halogen, 
     R 2  denotes alkyl or cycloalkyl, 
     X denotes COOR 3 , CON(R 4 ) 2 , COSR 3 , CN or ##STR2## R 3  denotes an alkali metal or alkaline earth metal, hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, or phenylalkyl, it being possible for phenyl to be substituted by halogen, or trialkylsilylalkyl or alkoxyalkyl, 
     the symbols R 4  independently of one another denote H, alkyl or cycloalkyl, which can be substituted, or 2 radicals R 4  together with the N atom linking them form a 4- to 7-membered heterocyclic ring and 
     n denotes 1 to 3, in combination with a herbicide.

This application is a division of application Ser. No. 07/912,659, filedon Jul. 13, 1992, now U.S. Pat. No. 5,401,700, which in turn was acontinuation of application Ser. No. 07/324,300, filed on Mar. 15, 1989now abandoned.

The present invention relates to agents for protecting crop plants fromthe phytotoxic side effects of herbicides, which agents contain acompound of the formula I ##STR3## wherein

Y denotes C--H or N, the symbols R₁ independently of one another denote(C₁ -C₄)-alkyl, (C₁ -C₄)-haloalkyl, (C₁ -C₄)-alkoxy, (C₁ -C₄)-haloalkoxyor halogen,

R₂ denotes (C₁ -C₁₂)-alkyl or (C₃ -C₇)-cycloalkyl,

X denotes COOR₃, CON(R₄)₂, COSR₃, CN or ##STR4##

R₃ denotes an alkali metal or alkaline earth metal, hydrogen, (C₁-C₁₀)-alkyl, (C₃ -C₂₀)-alkenyl, (C₃ -C₁₀)-alkynyl, (C₃ -C₇)-cycloalkylor phenyl-(C₁ -C₄)-alkyl, it being possible for phenyl to be substitutedby halogen, or tris-(C₁ -C₄)-alkyl-silyl-(C₁ -C₄)-alkyl or (C₁-C₄)-alkoxy-(C₁ -C₄)-alkyl,

the symbols R₄ independently of one another denote H, (C₁ -C₁₀)-alkyl or(C₃ -C₇)-cycloalkyl, which can be substituted, or 2 radicals R₄ togetherwith the N atom linking them form a 4- to 7-membered hetero-cyclic ringand

n denotes 1 to 3,

in combination with a herbicide.

In this formula, alkyl denotes straight-chain or branched alkyl.

In the case where X= ##STR5## two identical radicals of a compound ofthe formula I are linked to one another.

Halogen preferably denotes chlorine or bromine, alkali metal preferablydenotes Li, Na or K and alkaline earth metal denotes in particular Ca.The heterocyclic ring formed from the two radicals R₄ together with theN atom is preferably pyrrolidine, morpholine, 1,2,4-tri-azole orpiperidine.

The compounds of the formula I in which Y denotes CH, R₁ denotes halogenor (C₁ -C₄)-haloalkyl, R₂ denotes (C₁ -C₆)-alkyl, X denotes COOR₃, R₃denotes H or (C₁ -C₆)-alkyl and n denotes 1 or 2 are furthermorepreferred.

The compounds of the formula I in which Y denotes CH, R₁ denotes Cl, Bror CF₃, R₂ denotes (C₁ -C₄)-alkyl, X denotes COOR₃, R₃ denotes (C₁-C₄)-alkyl and n denotes 2 are particularly preferred.

The compounds of the formula I in which Y denotes CH, R₁ denotes2,4-Cl₂, R₂ denotes isopropyl, X denotes COOR₃ and R₃ denotes (C₁-C₁₀)-alkyl are novel and the present invention likewise relates tothem. In these compounds, the 5-position is preferred for R₂ and the3-position is preferred for X. The compound in which Y denotes CH, R₁denotes 2,4-Cl₂, R₂ denotes 5-isopropyl and X denotes 3-COOC₂ H₅ is ofparticular importance.

The compounds of the formula I can be prepared by methods which areknown from the Literature (HU-PS 153,762 or Chem. Abstr. 68, 87293 y(1968)). For further derivatization, the radical --COOR₃ is convertedinto other radicals mentioned for X in a known manner, for example byhydrolysis, transesterification, amidation, salt formation and the like,as is described, for example, in DE-OS 3,444,918 or 3,442,690.

When plant treatment agents, in particular herbicides, are used,undesirable damage which cannot be tolerated may occur to crop plants.On application of herbicides after emergence of the crop plants, inparticular, there is therefore often the need to avoid the risk ofpossible phytotoxicity.

Various compounds have already been described for this use (for exampleEP-A 152,006).

Surprisingly, it has been found that compounds of the formula I have theproperty of preventing or completely eliminating phytotoxic side effectsof plant protection agents, in particular herbicides, when used in cropsof useful plants. The compounds of the formula I are capable ofcompletely eliminating the harmful side effects of herbicides withoutcurtailing the activity of these herbicides against harmful plants.

Such compounds which have the property of protecting crop plants fromphytotoxic damage by herbicides without impairing the actual herbicidalaction of these agents are called "antidotes" or "safeners".

The field of use of conventional herbicides can be widened quiteconsiderably by addition of the safener compound of the formula I.

The present invention thus also relates to a method of protecting cropplants from the phytotoxic side effects of plant protection agents, inparticular herbicides, which comprises treating the plants, plant seedsor cultivation areas with a compound of the formula I before, after orat the same time as the plant protection agent.

Herbicides of which the phytotoxic side effects can be reduced by meansof the compounds of the formula I are, for example, carbamates,thiocarbamates, halogenoacetanilides, substituted phenoxy-, naphthoxy-and phenoxy-phenoxy-carboxylic acid derivatives andheteroaryloxy-phenoxycarboxylic acid derivatives, such as quinolyloxy-,quinoxalyloxy-, pyridyloxy-, benzoaxazolyloxy- andbenzo-thiazolyloxy-phenoxy-carboxylic acid esters, and furthermoredimedone oxime derivatives. Of these, phenoxy-phenoxy- andheteroaryloxyphenoxy-carboxylic acid esters are preferred. Possibleesters here are, in particular, lower alkyl, alkenyl and alkynyl esters.

The following herbicides may be mentioned as examples, without alimitation being intended by these:

A) Herbicides of the (C₁ -C₄)-alkyl, (C₂ -C₄)-alkenyl or (C₃-C₄)-alkynyl phenoxyphenoxy- and heteroaryl-oxyphenoxycarboxylate type,such as

methyl 2-(4-(2,4-dichlorophenoxy)-phenoxy)-propionate,

methyl 2-(4-(4-bromo-2-chlorophenoxy)-phenoxy)-propionate,

methyl 2-(4-(4-(4-trifuloromethylphenoxy)-phenoxy)-propionate,

methyl 2-(4-(2-chloro-4-trifluoromethylphenoxy)-phenoxy)-propionate,

methyl2-(4-(2,4-dichlorobenzyl)-phenoxy)-propionate,2-isopropylideneamino-oxyethyl(R)-2- 4(6-chloroquinoxalin-2-yloxy)-phenoxy!-propionate(propaquizafop),

ethyl 4-(4-(4-trifluoromethylphenoxy)-phenoxy)-pent-2-enoate,

ethyl 2-(4-(3,5-dichloropyridyl-2-oxy)-phenoxy)-propionate,

propargyl 2-(4-(3,5-dichloropyridyl-2-oxy)-phenoxy)-propionate,

ethyl 2-(4-(6-chlorobenzoxazol-2-yl-oxy)-phenoxy)-propionate,

ethyl 2(4-(6-chlorobenzothiazol-2-yl-oxy)-phenoxy)-propionate,

methyl2-(4-(3-chloro-5-trifluoromethyl-2-pyridyloxy)-phenoxy)-propionate,

butyl 2(4-(5-trifluoromethyl-2-pyridyloxy)-phenoxy)-propionate,

ethyl 2(4-(6-chloro-2-quinoxalyloxy)-phenoxy)-propionate,

ethyl 2-(4-(6-fluoro-2-quinoxalyloxy)-phenoxy)-propionate,

propargyl 2-(4-(5-chloro-3-fluoro-pyridyl-2-oxy)-phenoxy)-propionate,

ethyl 2-(4-(6-chloro-2-quinolyloxy)-phenoxy)-propionate,trimethylsilylmethyl2-(4-(3,5-dichloropyridyl-2-oxy)-phenoxy)-propionate,

ethyl2-(4-(3-chloro-5-trifluoromethoxy-2-pyridyloxy)-phenoxy)-propionate,

B) Chloroacetanilide herbicides, such as

N-methoxymethyl-2,6--diethyl-chloroacetanilide,

N-(3'-methoxyprop-2'-yl)-methyl-6-ethyl-chloroacetanilide and

N-(3-methyl-1,2,4-oxdiazol-5-yl-methyl)-chloroacetic acid2,6-dimethylanilide,

C) Thiocarbamates, such as

S-ethyl N,N-dipropylthiocarbamate or

S-ethyl N,N-diisobutylthiocarbamate

D) Dimedone derivatives, such as

2-(N-ethoxybutyrimidoyl)-5-(2-ethylthiopropyl)-3-hydroxy-2-cyclohexen-1-one

2-(N-ethoxybutyrimidoyl)-5-(2-phenylthiopropyl)-3-hydroxy-2-cyclohexen-1-one,

2-(1-allyloxyiminobutyl)-4-methoxycarbonyl-5,5-di-methyl-3-oxocyclohexenol,

2-(N-ethoxypropionamidoyl)-5-mesityl-3-hydroxy-2-cyclohexen-1-one,

2-(N-ethoxybutyrimidoyl)-3-hydroxy-5-(thian-3-yl)-2-cyclohexen-1-one,

2-1-(ethoxyimino)-butyl!-3-hydroxy-5-(2H-tetrahydro-thiopyran-3-yl)-2-cyclohexen-1-one(BASF 517),

2- 1-(ethoxyimino)-propyl!-3-hydroxy-5-mesitylcyclo-hex-2-enone (PP 604from ICI) and

(+)-2-(E)-3-chloroallyloxyiminopropyl!-5-(2-ethyl-thiopropyl)-3-hydroxycyclohex-2-enone(clethodim).

Of the herbicides which can be combined according to the invention withthe compounds of the formula I, the compounds listed under A) may bementioned as preferred, in particular ethyl2-(4-(6-chlorobenzoxazol-2-yl-oxy)-phenoxy)-propionate, ethyl2-(4-(6-chlorobenzothiazol-2-yl-oxy)-phenoxy)-propionate and propargyl2-(4-(5-chloro-3-fluoropyridyl-2-oxy)-phenoxy)-propionate. Of thesubstances mentioned under D),2-(N-ethoxypropionamidoyl)-5-mesityl-3-hydroxy-2-cyclohexen-1-one is ofparticular importance.

The ratio of the amounts of safener (compound I): herbicide can varywithin wide limits of between 1:10 and 10:1, in particular between 2:1and 1:10.

The particular optimum amounts of herbicide and safener depend on thetype of herbicide used or on the type of safener used and on the natureof the plant crop to be treated, and can be determined from case to caseby appropriate experiments.

The main fields of use for application of the safeners are, above all,cereal crops (wheat, rye, barley and oats), rice, maize and sorghum andalso cotton, sugar-beet, cane sugar and soya bean.

Depending on their properties, the safeners can be used for pretreatmentof the seeds of the crop plants (dressing of the seeds) or can beintroduced into the seed furrows before sowing or used together with theherbicide before or after emergence of the plants. Pre-emergencetreatment includes both treatment of the cultivation area before sowingand treatment of the sown cultivation areas on which there is as yet nogrowth.

However, simultaneous use of the antidote with the herbicide in the formof tank mixes or finished formulations is preferred.

The compounds of the formula I or the combination thereof with one ormore of the herbicides or herbicide groups mentioned can be formulatedin various ways as determined by the biological and/or chemical-physicalparameters. Suitable formulation possibilities are therefore: wettablepowders (WP), emulsifiable concentrates (EC), aqueous solutions (SC),emulsions, sprayable solutions, oil- or water-based dispersions (SC),suspoemulsions (SC), dusting agents (DP), dressing agents, granules inthe form of micro, spray, coated and adsorption granules,water-dispersible granules (WG), ULV formulations, microcapsules orwaxes.

These individual types of formulation are known in principle and aredescribed, for example, in: Winnacker-Kuchler, "Chemische Technologie(Chemical Technology)", Volume 7, C. Hauser Verlag Munchen, 4th edition1986; van Falkenberg, "Pesticides Formulations", Marcel Dekker N.Y., 2ndedition, 1972-73; and K. Martens, "Spray Drying Handbook", 3rd edition1979, G. Goodwin Ltd. London.

The formulation auxiliaries needed, such as inert materials,surfactants, solvents and other additives, are likewise known and aredescribed, for example, in: Watkins, "Handbook of Insecticide DustDiluents and Carriers", 2nd edition, Darland Books, Caldwell N.J.; H. V.Olphen, "Introduction to Clay Colloid Chemistry", 2nd edition, J. Wiley& Sons, N.Y.; Marschen, "Solvents Guide", 2nd edition, Interscience,N.Y. 1950; McCutcheon's, "Detergents and Emulsifiers Annual", MC Publ.Corp., Ridgewood N.J.; Sisley and Wood, "Encyclopedia of Surface ActiveAgents", Chem. Publ. Co. Inc., N.Y. 1964; Schonfeldt,"Grenzflachenaktive Athylenoxidaddukte (Surface-active ethylene oxideadducts)", Wiss. Verlagsgesell., Stuttgart 1976; and Winnacker-Kuchler,"Chemische Technologie (Chemical Technology)", Volume 7, C. HauserVerlag Munchen, 4th edition 1986.

On the basis of these formulations, it is also possible to preparecombinations with other pesticidally active substances, fertilizersand/or growth regulators, for example in the form of a finishedformulation or as a tank mix. Wettable powders are preparations whichare uniformly dispersible in water and, in addition to the activecompound and apart from a diluent or inert substance, also containwetting agents, for example polyoxyethylated alkylphenols,polyoxyethylated fatty alcohols and alkyl- or alkylphenol-sulfonate, anddispersing agents, for example sodium lignin-sulfonate, sodium2,2'-dinaphthylmethane-6,6'-disulfonate, sodiumdibutyl-naphthalene-sulfonate or sodium oleyl-methyl-taurate.Emulsifiable concentrates are prepared by dissolving the active compoundin an organic solvent, for example butonol, cyclohexanone,dimethylformamide, xylene or higher-boiling aromatics or hydrocarbons,with the addition of one or more emulsifiers. Examples of emulsifierswhich can be used are: calcium alkylarylsulfonates, such as Cadodecylbenzenesulfonate, or nonionic emulsifiers, such as fatty acidpolyglycol esters, alkylaryl poly-glycol ethers, fatty alcoholpolyglycol ethers, propylene oxide/ethylene oxide condensation products,alkyl poly-ethers, sorbitan fatty acid esters, polyoxyethylene sorbitanfatty acid esters or polyoxyethylene sorbitol esters. Dusts are obtainedby grinding the active compound with finely divided solid substances,for example talc or naturally occurring clays, such as kaolin,bentonite, pyrophyllite or diatomaceous earth. Granules can be preparedeither by spraying the active compound onto an adsorbent granular inertmaterial or by applying active compound concentrates to the surface ofcarrier substances, such as sand, kaolinites or a granular inertmaterial, by means of adhesives, for example polyvinyl alcohol, sodiumpolyacrylate or mineral oils. Suitable active compounds can also begranulated in the manner customary for the preparation of fertilizergranules--if desired as a mixture with fertilizers.

The active compound concentration in wettable powders is, for example,about 10 to 90% by weight, the remainder to make up to 100% by weightconsisting of customary formulation constituents. The active compoundconcentration in emulsifiable concentrates can be about 5 to 80% byweight. Dust-like formulations usually contain 5 to 20% by weight ofactive compound, and sprayable solutions contain about 2 to 20% byweight. In granules, the active compound content partly depends onwhether the active compound is in the liquid or solid form and on whatgranulation auxiliaries, fillers, and the like are used.

The active compound formulations mentioned additionally contain, ifappropriate, the particular customary tackifiers, wetting agents,dispersing agents, emulsifiers, penetration agents, solvents, fillers orcarrier substances.

For use, the concentrates in the commercially available form are dilutedin the customary manner if appropriate, for example by means of water inthe case of wettable powders, emulsifiable concentrates, dispersions andin some cases also microgranules. Dust-like and granular formulationsand sprayable solutions are usually not further diluted with more inertsubstances before use.

The application amount required for the compounds of the formula Ivaries according to the external conditions, such as temperature,humidity, nature of the herbicide used and others. It can vary withinwide limits, for example between 0.005 and 10.0 kg/ha or more of activesubstance, but is preferably between 0.01 and 5 kg/ha.

The following examples serve to illustrate the invention:

A. FORMULATION EXAMPLES

a) A dusting agent is obtained by mixing 10 parts by weight of acompound of the formula I and 90 parts by weight of talc or an inertsubstance and comminuting the mixture in an impact mill.

b) A wettable powder which is readily dispersible in water is obtainedby mixing 25 parts by weight of a compound of the formula I, 64 parts byweight of kaolin-containing quartz, as an inert substance, 10 parts byweight of potassium lignin-sulfonate and 1 part by weight of sodiumoleoyl-methyl-taurate, as the wetting and dispersing agents, andgrinding the mixture in a pinned disk mill.

c) A dispersion concentrate which is readily dispersible in water isobtained by mixing 20 parts by weight of a compound of the formula Iwith 6 parts by weight of alkylphenol polyglycol ether ((R) TritonX207), 3 parts by weight of isotridecanol polyglycol ether (8 mol ofethylene oxide) and 71 parts by weight of paraffinic mineral oil(boiling range, for example, about 255 to more than 277° C.) andgrinding the mixture to a fineness of less than 5 microns in a beadmill.

d) An emulsifiable concentrate is obtained from 15 parts by weight of acompound of the formula I, 75 parts by weight of cyclohexanone, as thesolvent, and 10 parts by weight of oxyethylated nonylphenol, as theemulsifier.

e) A concentrate which is readily emulsifiable in water and consists ofa phenoxycarboxylic acid ester and an antidote (10:1) is obtained from:

12.00% by weight of ethyl2-(4-(6-chlorobenzoxazol-2-yl-oxy)-phenoxy)-propionate

1.20% by weight of a compound of the formula I

69.00% by weight of xylene

7.80% by weight of calcium dodecylbenzenesulfonate

6.00% by weight of ethoxylated nonylphenol (10 mol of ethylene oxide)and

4.00% by weight of ethoxylated castor oil (40 mol of ethylene oxide)

The formulation is carried out as described under Example a).

f) A concentrate which is readily emulsifiable in water and consists ofa phenoxycarboxylic acid ester and an antidote (1:10) is obtained from:

4.0% by weight of ethyl2-(4-(6-chlorobenzoxazol-2-yl-oxy)-phenoxy)-propionate

40.0% by weight of a compound of the formula I

30.0% by weight of xylene

20.0% by weight of cyclohexanone

4.0% by weight of calcium dodecylbenzenesulfonate and

2.0% by weight of ethoxylated castor oil (40 mol of ethylene oxide)

B. CHEMICAL EXAMPLES 1. Ethyl1-(4-chlorophenyl)-5(3)-methyl-pyrazole-3(5)-carboxylate

14.3 g of 4-chlorophenylhydrazine II and 0.1 g of p-toluenesulfonic acidare added to 15.8 g of ethyl acetylpyruvate I in 100 ml of toluene withstirring and the mixture is heated, using a water separator. When nofurther water passes over, the mixture is allowed to cool and is dilutedwith 100 ml of toluene and washed with 100 ml of 3 N hydrochloric acid,100 ml of water, 100 ml of saturated NaHCO₃ solution and 100 ml ofwater, and the organic phase is concentrated to dryness andchromatographed over silica gel (mobile phase petroleum ether→ethylacetate).

Example No.

1 Ethyl 1-(4-chlorophenyl)-5-methyl-pyrazole-3-carboxylate (meltingpoint 121-124° C.)

62 Ethyl 1-(4-chlorophenyl)-3-methyl-pyrazole-5-carboxylate (oil)

Pyrazoles with a different substitution pattern in the aromatic partand/or a different allyl radical are prepared analogously and ifappropriate derivatized on the carbonyl function. The derivatives aresummarized in Table I.

                                      TABLE I                                     __________________________________________________________________________    Alkyl-aryl-pyrazolecarboxylic acid derivatives                                                                                     (I)                      1 #STR6##                                                                     Y = CH                                          Melting point/                Example                                         boiling point                 No.  (R.sub.1).sub.n                                                                          R.sub.2  X                      mm Hg  ° C.!           __________________________________________________________________________     2   4-Cl       5-CH.sub.3                                                                             3-COOCH.sub.3                                         3   "          "        3-COO-n-C.sub.3 H.sub.7                               4   "          "        3-COO-i-C.sub.3 H.sub.7                               5   "          "        3-COO-n-C.sub.4 H.sub.9                               6   "          "        3-COO-n-C.sub.5 H.sub.11                              7   "          "        3-COO-n-C.sub.6 H.sub.13                              8   "          "        3-COO-n-C.sub.8 H.sub.17                              9   "          "        3-COO-n-C.sub.10 H.sub.21                             10  "          "                                                                                      2 #STR7##                                             11  "          "        3-COOH                 157-160                        12  "          "        3-COOLi                                               13  "          "        3-COONa                                               14  "          "        3-COOK                                                15  "          "        3-COOCa.sub.1/2                                       16  "          "        3-COO-c-C.sub.4 H.sub.7                               17  "          "        3-COO-c-C.sub.6 H.sub.13                              18  "          "        3-COOCH.sub.2 --C.sub.6 H.sub.5                       19  "          "        3-COOCH.sub.2 -(2,4-Cl.sub.2 --C.sub.6 H.sub.3)       20  "          "        3-COOCH.sub.2 CHCH.sub.2                              21  "          "        3-COOC.sub.2 H.sub.4 CHCH.sub.2                       22  "          "        3-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                   23  "          "        3-COOCH.sub.2 CCH                                     24  "          "        3-COO--C.sub.2 H.sub.4 --CCH                          25  "          "        3-COO-n-C.sub.5 H.sub.10 CCH                          26  "          "        3-COOCH.sub.2 Si(CH.sub.3).sub.3                      27  "          "        3-COOC.sub.2 H.sub.4 OCH.sub.3                        28  "          "        3-CONH.sub.2                                          29  "          "        3-CN                                                  30  "          "        3-CONHCH.sub.3                                        31  "          "        3-CONHC.sub.2 H.sub.5                                 32  "          "        3-CONH-n-C.sub.3 H.sub.7                              33  "          "        3-CONH-n-C.sub.4 H.sub.9                              34  "          "        3-CONH-n-C.sub.6 H.sub.13                             35  "          "        3-CONH-n-C.sub.10 H.sub.21                            36  "          "        3-CONH-i-C.sub.3 H.sub.7                              37  "          "        3-CON(CH.sub.3).sub.2                                 38  "          "        3-CON(CH.sub.3)(nC.sub.6 H.sub.13)                    39  "          "        3-CON(C.sub.2 H.sub.5).sub.2                          40  "          "                                                                                      3 #STR8##                                             41  "          "                                                                                      4 #STR9##                                             42  "          "                                                                                      5 #STR10##                                            43  "          "                                                                                      6 #STR11##                                            44  "          "        3-CO--NH-c-C.sub.6 H.sub.11                           45  "          "        3-CO--NH-c-C.sub.3 H.sub.5                            46  "          "        3-CO--N(CH.sub.3)(cC.sub.6 H.sub.11)                  47  "          "        3-COSH                                                48  "          "        3-COSNa                                               49  "          "        3-COSCH.sub.3                                         50  "          "        3-COSC.sub.2 H.sub.5                                  51  "          "        3-COSCH.sub.2 C.sub.6 H.sub.5                         52  "          "        3-COS-nC.sub.8 H.sub.17                               53  "          "        3-COSC.sub.2 H.sub.4 OCH.sub.3                        54  "          "        3-COSCH.sub.2 CHCH.sub.2                              55  "          "        3-COSCH.sub.2 CCH                                     56  "          "        3-COS-c-C.sub.6 H.sub.11                              57  "          "        3-COSCH.sub.2 Si(CH.sub.3).sub.3                      58  "          "        3-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2            59  "          "                                                                                      7 #STR12##                                            60  "          "        3-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2               61  "          3-CH.sub.3                                                                             5-COOCH.sub.3                                         63  "          "        5-COOnC.sub.3 H.sub.7                                 64  "          "        5-COO-i-C.sub.3 H.sub.7                               65  "          "        5-COO-n-C.sub.4 H.sub.9                               66  "          "        5-COO-n-C.sub.5 H.sub.11                              67  "          "        5-COO-n-C.sub.6 H.sub.13                              68  "          "        5-COO-n-C.sub.8 H.sub.17                              69  "          "        5-COO-n-C.sub.10 H.sub.21                             70  "          "                                                                                      8 #STR13##                                            71  "          "        5-COOH                                                72  "          "        5-COOLi                                               73  "          "        5-COONa                                               74  "          "        5-COOK                                                75  "          "        5-COOCa.sub.1/2                                       76  "          "        5-COO-c-C.sub.4 H.sub.7                               77  "          "        5-COO-c-C.sub.6 H.sub.11                              78  "          "        5-COOCH.sub.2 --C.sub.6 H.sub.5                       79  "          "        5-COOCH.sub.2 -(2,4-Cl.sub.2 --C.sub.6 H.sub.3)       80  "          "        5-COOCH.sub.2 CHCH.sub.2                              81  "          "        5-COOC.sub.2 H.sub.4 CHCH.sub.2                       82  "          "        5-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                   83  "          "        5-COO--CH.sub.2 CCH                                   84  "          "        5-COO--C.sub.2 H.sub.4 --CCH                          85  "          "        5-COO-n-C.sub.5 H.sub.10 CCH                          86  "          "        5-COOCH.sub.2 Si(CH.sub.3).sub.3                      87  "          "        5-COOC.sub.2 H.sub.4 OCH.sub.3                        88  "          "        5-CONH.sub.2                                          89  "          "        5-CN                                                  90  "          "        5-CONHCH.sub.3                                        91  "          "        5-CONHC.sub.2 H.sub.5                                 92  "          "        5-CONH-n-C.sub.3 H.sub.7                              93  "          "        5-CONH-n-C.sub.4 H.sub.9                              94  "          "        5-CONH-n-C.sub.6 H.sub.13                             95  "          "        5-CONH-n-C.sub.10 H.sub.21                            96  "          "        5-CONH-i-C.sub.3 H.sub.7                              97  "          "        5-CON(CH.sub.3).sub.2                                 98  "          "        5-CON(CH.sub.3)(nC.sub.6 H.sub.13)                    99  "          "        5-CON(C.sub.2 H.sub.5).sub.2                         100  "          "                                                                                      9 #STR14##                                           101  "          "                                                                                      0 #STR15##                                           102  "          "                                                                                      1 #STR16##                                           103  "          "                                                                                      2 #STR17##                                           104  "          "        5-CO--NH-c-C.sub.6 H.sub.11                          105  "          "        5-CO--NH-c-C.sub.3 H.sub.5                           106  "          "        5-CO--N(CH.sub.3)(cC.sub.6 H.sub.11)                 107  "          "        5-COSH                                               108  "          "        5-COSNa                                              109  "          "        5-COSCH.sub.3                                        110  "          "        5-COSC.sub.2 H.sub.5                                 111  "          "        5-COSCH.sub.2 C.sub.6 H.sub.5                        112  "          "        5-COS-nC.sub.8 H.sub.17                              113  "          "        5-COSC.sub.2 H.sub.4 OCH.sub.3                       114  "          "        5-COSCH.sub.2 CHCH.sub.2                             115  "          "        5-COSCH.sub.2 CCH                                    116  "          "        5-COS-c-C.sub.6 H.sub.11                             117  "          "        5-COSCH.sub.2 Si(CH.sub.3).sub.3                     118  "          "        5-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2           119  "          "                                                                                      3 #STR18##                                           120  "          "        5-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2              121  2,4-Cl.sub.2                                                                             5-CH.sub.3                                                                             3-COOCH.sub.3          87-93                         122  "          "        3-COOC.sub.2 H.sub.5   78-81                         123  "          "        3-COO-n-C.sub.3 H.sub.7                                                                               99-100                       124  "          "        3-COO-i-C.sub.3 H.sub.7                                                                              65-70                         125  "          "        3-COO-n-C.sub.4 H.sub.9                                                                              76-78                         126  "          "        3-COO-n-C.sub.5 H.sub.11                             127  "          "        3-COO-n-C.sub.6 H.sub.13                                                                             Oil                           128  "          "        3-COO-n-C.sub.8 H.sub.17                                                                             47-49                         129  "          "        3-COO-n-C.sub.10 H.sub.21                            130  "          "                                                                                      2 #STR19##             114-117                       131  "          "        3-COOH                 112-115                       132  "          "        3-COOLi                >250                          133  "          "        3-COONa                >250                          134  "          "        3-COOK                                               135  "          "        3-COOCa.sub.1/2        187-188                       136  "          "        3-COO-c-C.sub.4 H.sub.7                              137  "          "        3-COO-c-C.sub.6 H.sub.11                                                                             72-74                         138  "          "        3-COOCH.sub.2 --C.sub.6 H.sub.5                                                                      Oil                           139  "          "        3-COOCH.sub.2 -(2,4-Cl.sub.2 --C.sub.6 H.sub.3)      140  "          "        3-COOCH.sub.2 CHCH.sub.2                                                                             Oil                           141  "          "        3-COOC.sub.2 H.sub.4 CHCH.sub.2                      142  "          "        3-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                  143  "          "        3-COO--CH.sub.2 CCH    101-102                       144  "          "        3-COO--C.sub.2 H.sub.4 --CCH                         145  "          "        3-COO-n-C.sub.5 H.sub.10 CCH                         146  "          "        3-COOCH.sub.2 Si(CH.sub.3).sub.3                                                                     67-70                         147  "          "        3-COOC.sub.2 H.sub.4 OCH.sub.3                                                                       Oil                           148  "          "        3-CONH.sub.2           161                           149  "          "        3-CN                                                 150  "          "        3-CONHCH.sub.3         161-162                       151  "          "        3-CONHC.sub.2 H.sub.5  87-90                         152  "          "        3-CONH-n-C.sub.3 H.sub.7                                                                             89-92                         153  "          "        3-CONH-n-C.sub.4 H.sub.9                                                                             55-60                         154  "          "        3-CONH-n-C.sub.6 H.sub.13                                                                            68-71                         155  "          "        3-CONH-n-C.sub.10 H.sub.21                           156  "          "        3-CONH-i-C.sub.3 H.sub.7                             157  "          "        3-CON(CH.sub.3).sub.2   99-103                       158  "          "        3-CON(CH.sub.3)(nC.sub.6 H.sub.13)                   159  "          "        3-CON(C.sub.2 H.sub.5).sub.2                                                                         Oil                           160  "          "                                                                                      3 #STR20##             Resin                         161  "          "                                                                                      4 #STR21##                                           162  "          "                                                                                      5 #STR22##             Oil                           163  "          "                                                                                      6 #STR23##             Resin                         164  "          "        3-CO--NH-c-C.sub.6 H.sub.11                                                                          120-122                       165  "          "        3-CO--NH-c-C.sub.3 H.sub.5                           166  "          "        3-CO--N(CH.sub.3)(cC.sub.6 H.sub.11)                                                                 Oil                           167  "          "        3-COSH                                               168  "          "        3-COSNa                                              169  "          "        3-COSCH.sub.3                                        170  "          "        3-COSC.sub.2 H.sub.5                                 171  "          "        3-COSCH.sub.2 C.sub.6 H.sub.5                                                                        70-73                         172  "          "        3-COS-nC.sub.8 H.sub.17                              173  "          "        3-COSC.sub.2 H.sub.4 OCH.sub.3                       174  "          "        3-COSCH.sub.2 CHCH.sub.2                             175  "          "        3-COSCH.sub.2 CCH                                    176  "          "        3-COS-c-C.sub.6 H.sub.11                             177  "          "        3-COSCH.sub.2 Si(CH.sub.3).sub.3                     178  "          "        3-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2           179  "          "                                                                                      7 #STR24##                                           180  "          "        3-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2              181  "          3-CH.sub.3                                                                             5-COOCH.sub.3                                        182  "          "        5-COOC.sub.2 H.sub.5   Oil                           183  "          "        5-COO-n-C.sub.3 H.sub.7                              184  "          "        5-COO-i-C.sub.3 H.sub.7                              185  "          "        5-COO-n-C.sub.4 H.sub.9                              186  "          "        5-COO-n-C.sub.5 H.sub.11                             187  "          "        5-COO-n-C.sub.6 H.sub.13                             188  "          "        5-COO-n-C.sub.8 H.sub.17                             189  "          "        5-COO-n-C.sub.10 H.sub.21                            190  "          "                                                                                      8 #STR25##                                           191  "          "        5-COOH                 195-205                       192  "          "        5-COOLi                                              193  "          "        5-COONa                                              194  "          "        5-COOK                                               195  "          "        5-COOCa.sub.1/2                                      196  "          "        5-COO-c-C.sub.4 H.sub.7                              197  "          "        5-COO-c-C.sub.6 H.sub.11                             198  "          "        5-COOCH.sub.2 --C.sub.6 H.sub.5                      199  "          "        5-COOCH.sub.2 -(2,4-Cl.sub.2 --C.sub.6 H.sub.3)      200  "          "        5-COOCH.sub.2 CHCH.sub.2                             201  "          "        5-COOC.sub.2 H.sub.4 CHCH.sub.2                      202  "          "        5-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                  203  "          "        5-COO--CH.sub.2 CCH                                  204  "          "        5-COO-C.sub.2 H.sub.4 --CCH                          205  "          "        5-COO-n-C.sub.5 H.sub.10 CCH                         206  "          "        5-COOCH.sub.2 Si(CH.sub.3).sub.3                     207  "          "        5-COOC.sub.2 H.sub.4 OCH.sub.3                       208  "          "        5-CONH.sub.2                                         209  "          "        5-CN                                                 210  "          "        5-CONHCH.sub.3                                       211  "          "        5-CONHC.sub.2 H.sub.5                                212  "          "        5-CONH-n-C.sub.3 H.sub.7                                                                             Oil                           213  "          "        5-CONH-n-C.sub.4 H.sub.9                             214  "          "        5-CONH-n-C.sub.6 H.sub.13                            215  "          "        5-CONH-n-C.sub.10 H.sub.21                           216  "          "        5-CONH-i-C.sub.3 H.sub.7                             217  "          "        5-CON(CH.sub.3).sub.2                                218  "          "        5-CON(CH.sub.3)(nC.sub.6 H.sub.13)                   219  "          "        5-CON(C.sub.2 H.sub.5).sub.2                         220  "          "                                                                                      9 #STR26##                                           221  "          "                                                                                      0 #STR27##                                           222  "          "                                                                                      1 #STR28##                                           223  "          "                                                                                      2 #STR29##                                           224  "          "        5-CO--NH-c-C.sub.6 H.sub.11                          225  "          "        5-CO--NH-c-C.sub.3 H.sub.5                           226  "          "        5-CO--N(CH.sub.3)(cC.sub.6 H.sub.11)                 227  "          "        5-COSH                                               228  "          "        5-COSNa                                              229  "          "        5-COSCH.sub.3                                        230  "          "        5-COSC.sub.2 H.sub.5                                 231  "          "        5-COSCH.sub.2 C.sub.6 H.sub.5                        232  "          "        5-COS-nC.sub.8 H.sub.17                              233  "          "        5-COSC.sub.2 H.sub.4 OCH.sub.3                       234  "          "        5-COSCH.sub.2 CHCH.sub.2                             235  "          "        5-COSCH.sub.2 CCH                                    236  "          "        5-COS-c-C.sub.6 H.sub.11                             237  "          "        5-COSCH.sub.2 Si(CH.sub.3).sub.3                     238  "          "        5-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2           239  "          "                                                                                      3 #STR30##                                           240  "          "        5-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2              241  "          5-C.sub.2 H.sub.5                                                                      3-COOCH.sub.3                                        242  "          "        3-COOC.sub.2 H.sub.5   48-49                         243  "          "        3-COO-n-C.sub.3 H.sub.7                              244  "          "        3-COO-i-C.sub.3 H.sub.7                              245  "          "        3-COO-n-C.sub.4 H.sub.9                              246  "          "        3-COO-n-C.sub.5 H.sub.11                             247  "          "        3-COO-n-C.sub.6 H.sub.13                             248  "          "        3-COO-n-C.sub.8 H.sub.17                             249  "          "        3-COO-n-C.sub.10 H.sub.21                            250  "          "                                                                                      2 #STR31##                                           251  "          "        3-COOH                 193-195                       252  "          "        3-COOLi                                              253  "          "        3-COONa                                              254  "          "        3-COOK                                               255  "          "        3-COOCa.sub.1/2                                      256  "          "        3-COO-c-C.sub.4 H.sub.7                              257  "          "        3-COO-c-C.sub.6 H.sub.11                             258  "          "        3-COOCH.sub.2 --C.sub.6 H.sub.5                      259  "          "        3-COOCH.sub.2 -(2,4-Cl.sub.2 --C.sub.6 H.sub.3)      260  "          "        3-COOCH.sub.2 CHCH.sub.2                             261  "          "        3-COOC.sub.2 H.sub.4 CHCH.sub.2                      262  "          "        3-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                  263  "          "        3-COO--CH.sub.2 CCH                                  264  "          "        3-CO--O--C.sub.2 H.sub.4 --CCH                       265  "          "        3-COO-n-C.sub.5 H.sub.10 CCH                         266  "          "        3-COOCH.sub.2 Si(CH.sub.3).sub.3                     267  "          "        3-COOC.sub.2 H.sub.4 OCH.sub.3                       268  "          "        3-CONH.sub.2                                         269  "          "        3-CN                                                 270  "          "        3-CONHCH.sub.3                                       271  "          "        3-CONHC.sub.2 H.sub.5                                272  "          "        3-CONH-n-C.sub.3 H.sub.7                             273  "          "        3-CONH-n-C.sub.4 H.sub.9                             274  "          "        3-CONH-n-C.sub.6 H.sub.13                            275  "          "        3-CONH-n-C.sub.10 H.sub.21                           276  "          "        3-CONH-i-C.sub.3 H.sub.7                             277  "          "        3-CON(CH.sub.3).sub.2                                278  "          "        3-CON(CH.sub.3)(nC.sub.6 H.sub.13)                   279  "          "        3-CON(C.sub.2 H.sub.5).sub.2                         280  "          "                                                                                      3 #STR32##                                           281  "          "                                                                                      4 #STR33##                                           282  "          "                                                                                      5 #STR34##                                           283  "          "                                                                                      6 #STR35##                                           284  "          "        3-CO--NH-c-C.sub.6 H.sub.11                          285  "          "        3-CO--NH-c-C.sub.3 H.sub.5                           286  "          "        3-CO--N(CH.sub.3)(cC.sub.6 H.sub.11)                 287  "          "        3-COSH                                               288  "          "        3-COSNa                                              289  "          "        3-COSCH.sub.3                                        290  "          "        3-COSC.sub.2 H.sub.5                                 291  "          "        3-COSCH.sub.2 C.sub.6 H.sub.5                        292  "          "        3-COS-nC.sub.8 H.sub.17                              293  "          "        3-COSC.sub.2 H.sub.4 OCH.sub.3                       294  "          "        3-COSCH.sub.2 CHCH.sub.2                             295  "          "        3-COSCH.sub.2 CCH                                    296  "          "        3-COS-c-C.sub.6 H.sub.11                             297  "          "        3-COSCH.sub.2 Si(CH.sub.3).sub.3                     298  "          "        3-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2           299  "          "                                                                                      7 #STR36##                                           300  "          "        3-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2              301  "          5-CH(CH.sub.3).sub.2                                                                   3-COOCH.sub.3          144                           302  "          "        3-COOC.sub.2 H.sub.5   70-77                         303  "          "        3-COO-n-C.sub.3 H.sub.7                                                                               0l                           304  "          "        3-COO-i-C.sub.3 H.sub.7                                                                               01                           305  "          "        3-COO-n-C.sub.4 H.sub.9                              306  "          "        3-COO-n-C.sub.5 H.sub.11                             307  "          "        3-COO-n-C.sub.6 H.sub.13                             308  "          "        3-COO-n-C.sub.8 H.sub.17                             309  "          "        3-COO-n-C.sub.10 H.sub.21                            310  "          "                                                                                      2 #STR37##                                           311  "          "        3-COOH                 195-196                       312  "          "        3-COOLi                                              313  "          "        3-COONa                >250                          314  "          "        3-COOK                                               315  "          "        3-COOCa.sub.1/2                                      316  "          "        3-COO-c-C.sub.4 H.sub.7                              317  "          "        3-COO-c-C.sub.6 H.sub.11                             318  "          "        3-COOCH.sub.2 --C.sub.6 H.sub.5                      319  "          "        3-COOCH.sub.2 -(2,4-Cl.sub.2 --C.sub.6 H.sub.3)      320  "          "        3-COOCH.sub.2 CHCH.sub.2                             321  "          "        3-COOC.sub.2 H.sub.4 CHCH.sub.2                      322  "          "        3-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                  323  "          "        3-COO--CH.sub.2 CCH                                  324  "          "        3-COO--C.sub.2 H.sub.4 --CCH                         325  "          "        3-COO-n-C.sub.5 H.sub.10 CCH                         326  "          "        3-COOCH.sub.2 Si(CH.sub.3).sub.3                     327  "          "        3-COOC.sub.2 H.sub.4 OCH.sub.3                       328  "          "        3-CONH.sub.2                                         329  "          "        3-CN                                                 330  "          "        3-CONHCH.sub.3                                       331  "          "        3-CONHC.sub.2 H.sub.5  106-109                       332  "          "        3-CONH-n-C.sub.3 H.sub.7                                                                              67                           333  "          "        3-CONH-n-C.sub.4 H.sub.9                             334  "          "        3-CONH-n-C.sub.6 H.sub.13                            335  "          "        3-CONH-n-C.sub.10 H.sub.21                           336  "          "        3-CONH-i-C.sub.3 H.sub.7                             337  "          "        3-CON(CH.sub.3).sub.2                                338  "          "        3-CON(CH.sub.3)(nC.sub.6 H.sub.13)                   339  "          "        3-CON(C.sub.2 H.sub.5).sub.2                                                                          98-100                       340  "          "                                                                                      3 #STR38##                                           341  "          "                                                                                      4 #STR39##                                           342  "          "                                                                                      5 #STR40##                                           343  "          "                                                                                      6 #STR41##             140-142                       344  "          "        3-CO--NH-c-C.sub.6 H.sub.11                          345  "          "        3-CO--NH-c-C.sub.3 H.sub.5                           346  "          "        3-CO--N(CH.sub.3)(cC.sub.6 H.sub.11)                 347  "          "        3-COSH                                               348  "          "        3-COSNa                                              349  "          "        3-COSCH.sub.3                                        350  "          "        3-COSC.sub.2 H.sub.5                                 351  "          "        3-COSCH.sub.2 C.sub.6 H.sub.5                        352  "          "        3-COS-nC.sub.8 H.sub.17                              353  "          "        3-COSC.sub.2 H.sub.4 OCH.sub.3                       354  "          "        3-COSCH.sub.2 CHCH.sub.2                             355  "          "        3-COSCH.sub.2 CCH                                    356  "          "        3-COS-c-C.sub.6 H.sub.11                             357  "          "        3-COSCH.sub.2 Si(CH.sub.3).sub.3                     358  "          "        3-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2           359  "          "                                                                                      7 #STR42##                                           360  "          "        3-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2              361  "          5-C(CH.sub.3).sub.3                                                                    3-COOCH.sub.3          Resin                         362  "          "        3-COOC.sub.2 H.sub.5   118-121                       363  "          "        3-COO-n-C.sub.3 H.sub.7                              364  "          "        3-COO-i-C.sub.3 H.sub.7                              365  "          "        3-COO-n-C.sub.4 H.sub.9                              366  "          "        3-COO-n-C.sub.5 H.sub.11                             367  "          "        3-COO-n-C.sub.6 H.sub.13                             368  "          "        3-COO-n-C.sub.8 H.sub.17                             369  "          "        3-COO-n-C.sub.10 H.sub.21                            370  "          "                                                                                      2 #STR43##                                           371  "          "        3-COOH                                               372  "          "        3-COOLi                                              373  "          "        3-COONa                                              374  "          "        3-COOK                                               375  "          "        3-COOCa.sub.1/2                                      376  "          "        3-COO-c-C.sub.4 H.sub.7                              377  "          "        3-COO-c-C.sub.6 H.sub.11                             378  "          "        3-COOCH.sub.2 --C.sub.6 H.sub.5                      379  "          "        3-COOCH.sub.2 -(2,4-Cl.sub.2 --C.sub.6 H.sub.3)      380  "          "        3-COOCH.sub.2 CHCH.sub.2                             381  "          "        3-COOC.sub.2 H.sub.4 CHCH.sub.2                      382  "          "        3-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                  383  "          "        3-COO--CH.sub.2 CCH                                  384  "          "        3-COO--C.sub.2 H.sub.4 --CCH                         385  "          "        3-COO-n-C.sub.5 H.sub.10 CCH                         386  "          "        3-COOCH.sub.2 Si(CH.sub.3).sub.3                     387  "          "        3-COOC.sub.2 H.sub.4 OCH.sub.3                       388  "          "        3-CONH.sub.2                                         389  "          "        3-CN                                                 390  "          "        3-CONHCH.sub.3                                       391  "          "        3-CONHC.sub.2 H.sub.5  161-162                       392  "          "        3-CONH-n-C.sub.3 H.sub.7                                                                             102-103                       393  "          "        3-CONH-n-C.sub.4 H.sub.9                             394  "          "        3-CONH-n-C.sub.6 H.sub.13                            395  "          "        3-CONH-n-C.sub.10 H.sub.21                           396  "          "        3-CONH-i-C.sub.3 H.sub.7                             397  "          "        3-CON(CH.sub.3).sub.2                                398  "          "        3-CON(CH.sub.3)(nC.sub.6 H.sub.13)                   399  "          "        3-CON(C.sub.2 H.sub.5).sub.2                         400  "          "                                                                                      3 #STR44##                                           401  "          "                                                                                      4 #STR45##                                           402  "          "                                                                                      5 #STR46##                                           403  "          "                                                                                      6 #STR47##                                           404  "          "        3-CO--NH-c-C.sub.6 H.sub.11                          405  "          "        3-CO--NH-c-C.sub.3 H.sub.5                           406  "          "        3-CO--N(CH.sub.3)(cC.sub.6 H.sub.11)                 407  "          "        3-COSH                                               408  "          "        3-COSNa                                              409  "          "        3-COSCH.sub.3                                        410  "          "        3-COSC.sub.2 H.sub.5                                 411  "          "        3-COSCH.sub.2 C.sub.6 H.sub.5                        412  "          "        3-COS-nC.sub.8 H.sub.17                              413  "          "        3-COSC.sub.2 H.sub.4 OCH.sub.3                       414  "          "        3-COSCH.sub.2 CHCH.sub.2                             415  "          "        3-COSCH.sub.2 CCH                                    416  "          "        3-COS-c-C.sub.6 H.sub.11                             417  "          "        3-COSCH.sub.2 Si(CH.sub.3).sub.3                     418  "          "        3-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2           419  "          "                                                                                      7 #STR48##                                           420  "          "        3-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2              421  "          5-CH.sub.2 --CH(CH.sub.3).sub.2                                                        3-COOCH.sub.3                                        422  "          "        3-COOC.sub.2 H.sub.5   Oil                           423  "          "        3-COO-n-C.sub.3 H.sub.7                              424  "          "        3-COO-i-C.sub.3 H.sub.7                              425  "          "        3-COO-n-C.sub.4 H.sub.9                              426  "          "        3-COO-n-C.sub.5 H.sub.11                             427  "          "        3-COO-n-C.sub.6 H.sub.13                             428  "          "        3-COO-n-C.sub.8 H.sub.17                             429  "          "        3-COO-n-C.sub.10 H.sub.21                            430  "          "                                                                                      2 #STR49##                                           431  "          "        3-COOH                                               432  "          "        3-COOLi                                              433  "          "        3-COONa                                              434  "          "        3-COOK                                               435  "          "        3-COOCa.sub.1/2                                      436  "          "        3-COO-c-C.sub.4 H.sub.7                              437  "          "        3-COO-c-C.sub.6 H.sub.11                             438  "          "        3-COOCH.sub.2 --C.sub.6 H.sub.5                      439  "          "        3-COOCH.sub.2 -(2,4-Cl.sub.2 --C.sub.6 H.sub.3)      440  "          "        3-COOCH.sub.2 CHCH.sub.2                             441  "          "        3-COOC.sub.2 H.sub.4 CHCH.sub.2                      442  "          "        3-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                  443  "          "        3-COO--CH.sub.2 CCH                                  444  "          "        3-COO--C.sub.2 H.sub.4 --CCH                         445  "          "        3-COO-n-C.sub.5 H.sub.10 CCH                         446  "          "        3-COOCH.sub.2 Si(CH.sub.3).sub.3                     447  "          "        3-COOC.sub.2 H.sub.4 OCH.sub.3                       448  "          "        3-CONH.sub.2                                         449  "          "        3-CN                                                 450  "          "        3-CONHCH.sub.3                                       451  "          "        3-CONHC.sub.2 H.sub.5                                452  "          "        3-CONH-n-C.sub.3 H.sub.7                             453  "          "        3-CONH-n-C.sub.4 H.sub.9                             454  "          "        3-CONH-n-C.sub.6 H.sub.13                            455  "          "        3-CONH-n-C.sub.10 H.sub.21                           456  "          "        3-CONH-i-C.sub.3 H.sub.7                             457  "          "        3-CON(CH.sub.3).sub.2                                458  "          "        3-CON(CH.sub.3)(nC.sub.6 H.sub.13)                   459  "          "        3-CON(C.sub.2 H.sub.5).sub.2                         460  "          "                                                                                      3 #STR50##                                           461  "          "                                                                                      4 #STR51##                                           462  "          "                                                                                      5 #STR52##                                           463  "          "                                                                                      6 #STR53##                                           464  "          "        3-CO--NH-c-C.sub.6 H.sub.11                          465  "          "        3-CO--NH-c-C.sub.3 H.sub.5                           466  "          "        3-CO--N(CH.sub.3)(cC.sub.6 H.sub.11)                 467  "          "        3-COSH                                               468  "          "        3-COSNa                                              469  "          "        3-COSCH.sub.3                                        470  "          "        3-COSC.sub.2 H.sub.5                                 471  "          "        3-COSCH.sub.2 C.sub.6 H.sub.5                        472  "          "        3-COS-nC.sub.8 H.sub.17                              473  "          "        3-COSC.sub.2 H.sub.4 OCH.sub.3                       474  "          "        3-COSCH.sub.2 CHCH.sub.2                             475  "          "        3-COSCH.sub.2 CCH                                    476  "          "        3-COS-c-C.sub.6 H.sub.11                             477  "          "        3-COSCH.sub.2 Si(CH.sub.3).sub.3                     478  "          "        3-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2           479  "          "                                                                                      7 #STR54##                                           480  "          "        3-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2              481  "          5-c-C.sub.6 H.sub.11                                                                   3-COOCH.sub.3                                        482  "          "        3-COOC.sub.2 H.sub.5   106-108                       483  "          "        3-COO-n-C.sub.3 H.sub.7                              484  "          "        3-COO-i-C.sub.3 H.sub.7                              485  "          "        3-COO-n-C.sub.4 H.sub.9                              486  "          "        3-COO-n-C.sub.5 H.sub.11                             487  "          "        3-COO-n-C.sub.6 H.sub.13                             488  "          "        3-COO-n-C.sub.8 H.sub.17                             489  "          "        3-COO-n-C.sub.10 H.sub.21                            490  "          "                                                                                      2 #STR55##                                           491  "          "        3-COOH                 201-202                       492  "          "        3-COOLi                                              493  "          "        3-COONa                                              494  "          "        3-COOK                                               495  "          "        3-COOCa.sub.1/2                                      496  "          "        3-COO-c-C.sub.4 H.sub.7                              497  "          "        3-COO-c-C.sub.6 H.sub.11                             498  "          "        3-COOCH.sub.2 --C.sub.6 H.sub.5                      499  "          "        3-COOCH.sub.2 -(2,4-Cl.sub.2 --C.sub.6 H.sub.3)      500  "          "        3-COOCH.sub.2 CHCH.sub.2                             501  "          "        3-COOC.sub.2 H.sub.4 CHCH.sub.2                      502  "          "        3-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                  503  "          "        3-COO--CH.sub.2 CCH                                  504  "          "        3-COO--C.sub.2 H.sub.4 --CCH                         505  "          "        3-COO-n-C.sub.5 H.sub.10 CCH                         506  "          "        3-COOCH.sub.2 Si(CH.sub.3).sub.3                     507  "          "        3-COOC.sub.2 H.sub.4 OCH.sub.3                       508  "          "        3-CONH.sub.2                                         509  "          "        3-CN                                                 510  "          "        3-CONHCH.sub.3                                       511  "          "        3-CONHC.sub.2 H.sub.5  131-132                       512  "          "        3-CONH-n-C.sub.3 H.sub.7                             513  "          "        3-CONH-n-C.sub.4 H.sub.9                             514  "          "        3-CONH-n-C.sub.6 H.sub.13                            515  "          "        3-CONH-n-C.sub.10 H.sub.21                           516  "          "        3-CONH-i-C.sub.3 H.sub.7                             517  "          "        3-CON(CH.sub.3).sub.2                                518  "          "        3-CON(CH.sub.3)(nC.sub.6 H.sub.13)                   519  "          "        3-CON(C.sub.2 H.sub.5).sub.2                         520  "          "                                                                                      3 #STR56##                                           521  "          "                                                                                      4 #STR57##                                           522  "          "                                                                                      5 #STR58##                                           523  "          "                                                                                      6 #STR59##                                           524  "          "        3-CO--NH-c-C.sub.6 H.sub.11                          525  "          "        3-CO--NH-c-C.sub.3 H.sub.5                           526  "          "        3-CO--N(CH.sub.3)(cC.sub.6 H.sub.11)                 527  "          "        3-COSH                                               528  "          "        3-COSNa                                              529  "          "        3-COSCH.sub.3                                        530  "          "        3-COSC.sub.2 H.sub.5                                 531  "          "        3-COSCH.sub.2 C.sub.6 H.sub.5                        532  "          "        3-COS-nC.sub.8 H.sub.17                              533  "          "        3-COSC.sub.2 H.sub.4 OCH.sub.3                       534  "          "        3-COSCH.sub.2 CHCH.sub.2                             535  "          "        3-COSCH.sub.2 CCH                                    536  "          "        3-COS-c-C.sub.6 H.sub.11                             537  "          "        3-COSCH.sub.2 Si(CH.sub.3).sub.3                     538  "          "        3-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2           539  "          "                                                                                      7 #STR60##                                           540  "          "        3-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2              541  2,4-Br.sub.2                                                                             5-CH.sub.3                                                                             3-COOCH.sub.3                                        542  "          "        3-COOC.sub.2 H.sub.5    91-100                       543  "          "        3-COO-n-C.sub.3 H.sub.7                              544  "          "        3-COO-i-C.sub.3 H.sub.7                              545  "          "        3-COO-n-C.sub.4 H.sub.9                              546  "          "        3-COO-n-C.sub.5 H.sub.11                             547  "          "        3-COO-n-C.sub.6 H.sub.13                             548  "          "        3-COO-n-C.sub.8 H.sub.17                             549  "          "        3-COO-n-C.sub.10 H.sub.21                            550  "          "                                                                                      2 #STR61##                                           551  "          "        3-COOH                                               552  "          "        3-COOLi                                              553  "          "        3-COONa                                              554  "          "        3-COOK                                               555  "          "        3-COOCa.sub.1/2                                      556  "          "        3-COO-c-C.sub.4 H.sub.7                              557  "          "        3-COO-c-C.sub.6 H.sub.11                             558  "          "        3-COOCH.sub.2 --C.sub.6 H.sub.5                      559  "          "        3-COOCH.sub.2 -(2,4-Cl.sub.2 --C.sub.6 H.sub.3)      560  "          "        3-COOCH.sub.2 CHCH.sub.2                             561  "          "        3-COOC.sub.2 H.sub.4 CHCH.sub.2                      562  "          "        3-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                  563  "          "        3-COO--CH.sub.2 CCH                                  564  "          "        3-COO--C.sub.2 H.sub.4 --CCH                         565  "          "        3-COO-n-C.sub.5 H.sub.10 CCH                         566  "          "        3-COOCH.sub.2 Si(CH.sub.3).sub.3                     567  "          "        3-COOC.sub.2 H.sub.4 OCH.sub.3                       568  "          "        3-CONH.sub.2                                         569  "          "        3-CN                                                 570  "          "        3-CONHCH.sub.3                                       571  "          "        3-CONHC.sub.2 H.sub.5                                572  "          "        3-CONH-n-C.sub.3 H.sub.7                             573  "          "        3-CONH-n-C.sub.4 H.sub.9                             574  "          "        3-CONH-n-C.sub.6 H.sub.13                            575  "          "        3-CONH-n-C.sub.10 H.sub.21                           576  "          "        3-CONH-i-C.sub.3 H.sub.7                             577  "          "        3-CON(CH.sub.3).sub.2                                578  "          "        3-CON(CH.sub.3)(nC.sub.6 H.sub.13)                   579  "          "        3-CON(C.sub.2 H.sub.5).sub.2                         580  "          "                                                                                      3 #STR62##                                           581  "          "                                                                                      4 #STR63##                                           582  "          "                                                                                      5 #STR64##                                           583  "          "                                                                                      6 #STR65##                                           584  "          "        3-CO--NH-c-C.sub.6 H.sub.11                          585  "          "        3-CO--NH-c-C.sub.3 H.sub.5                           586  "          "        3-CO--N(CH.sub.3)(cC.sub.6 H.sub.11)                 587  "          "        3-COSH                                               588  "          "        3-COSNa                                              589  "          "        3-COSCH.sub.3                                        590  "          "        3-COSC.sub.2 H.sub.5                                 591  "          "        3-COSCH.sub.2 C.sub.6 H.sub.5                        592  "          "        3-COS-nC.sub.8 H.sub.17                              593  "          "        3-COSC.sub.2 H.sub.4 OCH.sub.3                       594  "          "        3-COSCH.sub.2 CHCH.sub.2                             595  "          "        3-COSCH.sub.2 CCH                                    596  "          "        3-COS-c-C.sub.6 H.sub.11                             597  "          "        3-COSCH.sub.2 Si(CH.sub.3).sub.3                     598  "          "        3-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2           599  "          "                                                                                      7 #STR66##                                           600  "          "        3-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2              601  3-CF.sub.3 "        3-COOCH.sub.3                                        602  "          "        3-COOC.sub.2 H.sub.5   73-75                         603  "          "        3-COO-n-C.sub.3 H.sub.7                              604  "          "        3-COO-i-C.sub.3 H.sub.7                              605  "          "        3-COO-n-C.sub.4 H.sub.9                                                                               0l                           606  "          "        3-COO-n-C.sub.5 H.sub.11                             607  "          "        3-COO-n-C.sub.6 H.sub.13                             608  "          "        3-COO-n-C.sub.8 H.sub.17                             609  "          "        3-COO-n-C.sub.10 H.sub.21                            610  "          "                                                                                      2 #STR67##                                           611  "          "        3-COOH                 190-191                       612  "          "        3-COOLi                                              613  "          "        3-COONa                                              614  "          "        3-COOK                                               615  "          "        3-COOCa.sub.1/2                                      616  "          "        3-COO-c-C.sub.4 H.sub.7                              617  "          "        3-COO-c-C.sub.6 H.sub.11                             618  "          "        3-COOCH.sub.2 --C.sub.6 H.sub.5                      619  "          "        3-COOCH.sub.2 -(2,4-Cl.sub.2 --C.sub.6 H.sub.3)      620  "          "        3-COOCH.sub.2 CHCH.sub.2                             621  "          "        3-COOC.sub.2 H.sub.4 CHCH.sub.2                      622  "          "        3-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                  623  "          "        3-COO--H.sub.2 CCH                                   624  "          "        3-COO--C.sub.2 H.sub.4 --CCH                         625  "          "        3-COO-n-C.sub.5 H.sub.10 CCH                         626  "          "        3-COOCH.sub.2 Si(CH.sub.3).sub.3                     627  "          "        3-COOC.sub.2 H.sub.4 OCH.sub.3                       628  "          "        3-CONH.sub.2                                         629  "          "        3-CN                                                 630  "          "        3-CONHCH.sub.3                                       631  "          "        3-CONHC.sub.2 H.sub.5                                632  "          "        3-CONH-n-C.sub.3 H.sub.7                                                                             66 72                         633  "          "        3-CONH-n-C.sub.4 H.sub.9                             634  "          "        3-CONH-n-C.sub.6 H.sub.13                            635  "          "        3-CONH-n-C.sub.10 H.sub.21                           636  "          "        3-CONH-i-C.sub.3 H.sub.7                             637  "          "        3-CON(CH.sub.3).sub.2                                638  "          "        3-CON(CH.sub.3)(nC.sub.6 H.sub.13)                   639  "          "        3-CON(C.sub.2 H.sub.5).sub.2                         640  "          "                                                                                      3 #STR68##                                           641  "          "                                                                                      4 #STR69##                                           642  "          "                                                                                      5 #STR70##                                           643  "          "                                                                                      6 #STR71##                                           644  "          "        3-CO--NH-c-C.sub.6 H.sub.11                          645  "          "        3-CO--NH-c-C.sub.3 H.sub.5                           646  "          "        3-CO--N(CH.sub.3)(cC.sub.6 H.sub.11)                 647  "          "        3-COSH                                               648  "          "        3-COSNa                                              649  "          "        3-COSCH.sub.3                                        650  "          "        3-COSC.sub.2 H.sub.5                                 651  "          "        3-COSCH.sub.2 C.sub.6 H.sub.5                        652  "          "        3-COS-nC.sub.8 H.sub.17                              653  "          "        3-COSC.sub.2 H.sub.4 OCH.sub.3                       654  "          "        3-COSCH.sub.2 CHCH.sub.2                             655  "          "        3-COSCH.sub.2 CCH                                    656  "          "        3-COS-c-C.sub.6 H.sub.11                             657  "          "        3-COSCH.sub.2 Si(CH.sub.3).sub.3                     658  "          "        3-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2           659  "          "                                                                                      7 #STR72##                                           660  "          "        3-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2              661  2,4-ClCF.sub.3                                                                           "        3-CONHC.sub.2 H.sub.5                                662  "          "        3-CONH-n-C.sub.3 H.sub.7                                                                             109-113                       663  "          "        3-CONH-n-C.sub.4 H.sub.9                             664  "          "        3-CONH-n-C.sub.6 H.sub.13                            665  "          "        3-CONH-n-C.sub.10 H.sub.21                           666  "          "        3-CONH-i-C.sub.3 H.sub.7                             667  "          "        3-CON(CH.sub.3).sub.2                                668  "          "        3-CON(CH.sub.3)(nC.sub.6 H.sub.13)                   669  "          "        3-CON(C.sub.2 H.sub.5).sub.2                         670  "          "                                                                                      3 #STR73##                                           671  "          "                                                                                      4 #STR74##                                           672  "          "                                                                                      5 #STR75##                                           673  "          "                                                                                      6 #STR76##                                           674  "          "        3-CO--NH-c-C.sub.6 H.sub.11                          675  "          "        3-CO--NH-c-C.sub.3 H.sub.5                           676  "          "        3-CO--N(CH.sub.3)(cC.sub.6 H.sub.11)                 677  "          "        3-COSH                                               678  "          "        3-COSNa                                              679  "          "        3-COSCH.sub.3                                        680  "          "        3-COSC.sub.2 H.sub.5                                 681  "          "        3-COSCH.sub.2 C.sub.6 H.sub.5                        682  "          "        3-COS-nC.sub.8 H.sub.17                              683  "          "        3-COSC.sub.2 H.sub.4 OCH.sub.3                       684  "          "        3-COSCH.sub.2 CHCH.sub.2                             685  "          "        3-COSCH.sub.2 CCH                                    686  "          "        3-COS-c-C.sub.6 H.sub.11                             687  "          "        3-COSCH.sub.2 Si(CH.sub.3).sub.3                     688  "          "        3-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2           689  "          "                                                                                      7 #STR77##                                           690  "          "        3-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2              691  "          "        3-COOCH.sub.3                                        692  "          "        3-COOC.sub.2 H.sub.5                                 693  "          "        3-COO-n-C.sub.3 H.sub.7                              694  "          "        3-COO-i-C.sub.3 H.sub.7                              695  "          "        3-COO-n-C.sub.4 H.sub.9                              696  "          "        3-COO-n-C.sub.5 H.sub.11                             697  "          "        3-COO-n-C.sub.6 H.sub.13                             698  "          "        3-COO-n-C.sub.8 H.sub.17                             699  "          "        3-COO-n-C.sub.10 H.sub.21                            700  "          "                                                                                      2 #STR78##                                           701  "          "        3-COOH                                               702  "          "        3-COOLi                                              703  "          "        3-COONa                                              704  "          "        3-COOK                                               705  "          "        3-COOCa.sub.1/2                                      706  "          "        3-COO-c-C.sub.4 H.sub.7                              707  "          "        3-COO-c-C.sub.6 H.sub.11                             708  "          "        3-COOCH.sub.2 --C.sub.6 H.sub.5                      709  "          "        3-COOCH.sub.2 -(2,4-Cl.sub.2 --C.sub.6 H.sub.3)      710  "          "        3-COOCH.sub.2 CHCH.sub.2                             711  "          "        3-COOC.sub.2 H.sub.4 CHCH.sub.2                      712  "          "        3-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                  713  "          "        3-COO--CH.sub.2 CCH                                  714  "          "        3-COO--C.sub.2 H.sub.4 --CCH                         715  "          "        3-COO-n-C.sub.5 H.sub.10 CCH                         716  "          "        3-COOCH.sub.2 Si(CH.sub.3).sub.3                     717  "          "        3-COOC.sub.2 H.sub.4 OCH.sub.3                       718  "          "        3-CONH.sub.2                                         719  "          "        3-CN                                                 720  "          "        3-CONHCH.sub.3                                       721  4,2-ClCF.sub.3                                                                           "        3-COOCH.sub.3                                        722  "          "        3-COOC.sub.2 H.sub.5   49-51                         723  "          "        3-COO-n-C.sub.3 H.sub.7                              724  "          "        3-COO-i-C.sub.3 H.sub.7                              725  "          "        3-COO-n-C.sub.4 H.sub.9                              726  "          "        3-COO-n-C.sub.5 H.sub.11                             727  "          "        3-COO-n-C.sub.6 H.sub.13                             728  "          "        3-COO-n-C.sub.8 H.sub.17                             729  "          "        3-COO-n-C.sub.10 H.sub.21                            730  "          "                                                                                      2 #STR79##                                           731  "          "        3-COOH                                               732  "          "        3-COOLi                                              733  "          "        3-COONa                                              734  "          "        3-COOK                                               735  "          "        3-COOCa.sub.1/2                                      736  "          "        3-COO-c-C.sub.4 H.sub.7                              737  "          "        3-COO-c-C.sub.6 H.sub.11                             738  "          "        3-COOCH.sub.2 --C.sub.6 H.sub.5                      739  "          "        3-COOCH.sub.2 -(2,4-Cl.sub.2 --C.sub.6 H.sub.3)      740  "          "        3-COOCH.sub.2 CHCH.sub.2                             741  "          "        3-COOC.sub.2 H.sub.4 CHCH.sub.2                      742  "          "        3-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                  743  "          "        3-COO--H.sub.2 CCH                                   744  "          "        3-COO--C.sub.2 H.sub.4 --CCH                         745  "          "        3-COO-n-C.sub.5 H.sub.10 CCH                         746  "          "        3-COOCH.sub.2 Si(CH.sub.3).sub.3                     747  "          "        3-COOC.sub.2 H.sub.4 OCH.sub.3                       748  "          "        3-CONH.sub.2                                         749  "          "        3-CN                                                 750  "          "        3-CONHCH.sub.3                                       751  "          "        3-CONHC.sub.2 H.sub.5                                752  "          "        3-CONH-n-C.sub.3 H.sub.7                             753  "          "        3-CONH-n-C.sub.4 H.sub.9                             754  "          "        3-CONH-n-C.sub.6 H.sub.13                            755  "          "        3-CONH-n-C.sub.10 H.sub.21                           756  "          "        3-CONH-i-C.sub.3 H.sub.7                             757  "          "        3-CON(CH.sub.3).sub.2                                758  "          "        3-CON(CH.sub.3)(nC.sub.6 H.sub.13)                   759  "          "        3-CON(C.sub.2 H.sub.5).sub.2                         760  "          "                                                                                      3 #STR80##                                           761  "          "                                                                                      4 #STR81##                                           762  "          "                                                                                      5 #STR82##                                           763  "          "                                                                                      6 #STR83##                                           764  "          "        3-CO--NH-c-C.sub.6 H.sub.11                          765  "          "        3-CO--NH-c-C.sub.3 H.sub.5                           766  "          "        3-CO--N(CH.sub.3)(cC.sub.6 H.sub.11)                 767  "          "        3-COSH                                               768  "          "        3-COSNa                                              769  "          "        3-COSCH.sub.3                                        770  "          "        3-COSC.sub.2 H.sub.5                                 771  "          "        3-COSCH.sub.2 C.sub.6 H.sub.5                        772  "          "        3-COS-nC.sub.8 H.sub.17                              773  "          "        3-COSC.sub.2 H.sub.4 OCH.sub.3                       774  "          "        3-COSCH.sub.2 CHCH.sub.2                             775  "          "        3-COSCH.sub.2 CCH                                    776  "          "        3-COS-c-C.sub.6 H.sub.11                             777  "          "        3-COSCH.sub.2 Si(CH.sub.3).sub.3                     778  "          "        3-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2           779  "          "                                                                                      7 #STR84##                                           780  "          "        3-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2              781  2,6,4-Cl.sub.2 CF.sub.3                                                                  "        3-COOCH.sub.3                                        782  "          "        3-COOC.sub.2 H.sub.5   138-140                       783  "          "        3-COO-n-C.sub.3 H.sub.7                              784  "          "        3-COO-i-C.sub.3 H.sub.7                              785  "          "        3-COO-n-C.sub.4 H.sub.9                              786  "          "        3-COO-n-C.sub.5 H.sub.11                             787  "          "        3-COO-n-C.sub.6 H.sub.13                             788  "          "        3-COO-n-C.sub.8 H.sub.17                             789  "          "        3-COO-n-C.sub.10 H.sub.21                            790  "          "                                                                                      2 #STR85##                                           791  "          "        3-COOH                                               792  "          "        3-COOLi                                              793  "          "        3-COONa                                              794  "          "        3-COOK                                               795  "          "        3-COOCa.sub.1/2                                      796  "          "        3-COO-c-C.sub.4 H.sub.7                              797  "          "        3-COO-c-C.sub.6 H.sub.11                             798  "          "        3-COOCH.sub.2 --C.sub.6 H.sub.5                      799  "          "        3-COOCH.sub.2 -(2,4-Cl.sub.2 --C.sub.6 H.sub.3)      800  "          "        3-COOCH.sub.2 CHCH.sub.2                             801  "          "        3-COOC.sub.2 H.sub.4 CHCH.sub.2                      802  "          "        3-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                  803  "          "        3-COO--CH.sub.2 CCH                                  804  "          "        3-COO--C.sub.2 H.sub.4 --CCH                         805  "          "        3-COO-n-C.sub.5 H.sub.10 CCH                         806  "          "        3-COOCH.sub.2 Si(CH.sub.3).sub.3                     807  "          "        3-COOC.sub.2 H.sub.4 OCH.sub.3                       808  "          "        3-CONH.sub.2                                         809  "          "        3-CN                                                 810  "          "        3-CONHCH.sub.3                                       811  "          "        3-CONHC.sub.2 H.sub.5                                812  "          "        3-CONH-n-C.sub.3 H.sub.7                             813  "          "        3-CONH-n-C.sub.4 H.sub.9                             814  "          "        3-CONH-n-C.sub.6 H.sub.13                            815  "          "        3-CONH-n-C.sub.10 H.sub.21                           816  "          "        3-CONH-i-C.sub.3 H.sub.7                             817  "          "        3-CON(CH.sub.3).sub.2                                818  "          "        3-CON(CH.sub.3)(nC.sub.6 H.sub.13)                   819  "          "        3-CON(C.sub.2 H.sub.5).sub.2                         820  "          "                                                                                      3 #STR86##                                           821  "          "                                                                                      4 #STR87##                                           822  "          "                                                                                      5 #STR88##                                           823  "          "                                                                                      6 #STR89##                                           824  "          "        3-CO--NH-c-C.sub.6 H.sub.11                          825  "          "        3-CO--NH-c-C.sub.3 H.sub.5                           826  "          "        3-CO--N(CH.sub.3)(cC.sub.6 H.sub.11)                 827  "          "        3-COSH                                               828  "          "        3-COSNa                                              829  "          "        3-COSCH.sub.3                                        830  "          "        3-COSC.sub.2 H.sub.5                                 831  "          "        3-COSCH.sub.2 C.sub.6 H.sub.5                        832  "          "        3-COS-nC.sub.8 H.sub.17                              833  "          "        3-COSC.sub.2 H.sub.4 OCH.sub.3                       834  "          "        3-COSCH.sub.2 CHCH.sub.2                             835  "          "        3-COSCH.sub.2 CCH                                    836  "          "        3-COS-c-C.sub.6 H.sub.11                             837  "          "        3-COSCH.sub.2 Si(CH.sub.3).sub.3                     838  "          "        3-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2           839  "          "                                                                                      7 #STR90##                                           840  "          "        3-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2              841  3,5-Cl--CF.sub.3                                                                         "        3-COOCH.sub.3                                        842  "          "        3-COOC.sub.2 H.sub.5   55-58                         843  "          "        3-COO-n-C.sub.3 H.sub.7                              844  "          "        3-COO-i-C.sub.3 H.sub.7                              845  "          "        3-COO-n-C.sub.4 H.sub.9                              846  "          "        3-COO-n-C.sub.5 H.sub.11                             847  "          "        3-COO-n-C.sub.6 H.sub.13                             848  "          "        3-COO-n-C.sub.8 H.sub.17                             849  "          "        3-COO-n-C.sub.10 H.sub.21                            850  "          "                                                                                      2 #STR91##                                           851  "          "        3-COOH                                               852  "          "        3-COOLi                                              853  "          "        3-COONa                                              854  "          "        3-COOK                                               855  "          "        3-COOCa.sub.1/2                                      856  "          "        3-COO-c-C.sub.4 H.sub.7                              857  "          "        3-COO-c-C.sub.6 H.sub.11                             858  "          "        3-COOCH.sub.2 --C.sub.6 H.sub.5                      859  "          "        3-COOCH.sub.2 -(2,4-Cl.sub.2 --C.sub.6 H.sub.3)      860  "          "        3-COOCH.sub.2 CHCH.sub.2                             861  "          "        3-COOC.sub.2 H.sub.4 CHCH.sub.2                      862  "          "        3-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                  863  "          "        3-COO--CH.sub.2 CCH                                  864  "          "        3-COO--C.sub.2 H.sub.4 --CCH                         865  "          "        3-COO-n-C.sub.5 H.sub.10 CCH                         866  "          "        3-COOCH.sub.2 Si(CH.sub.3).sub.3                     867  "          "        3-COOC.sub.2 H.sub.4 OCH.sub.3                       868  "          "        3-CONH.sub.2                                         869  "          "        3-CN                                                 870  "          "        3-CONHCH.sub.3                                       871  3,5-ClCF.sub.3                                                                           "        3-CONHC.sub.2 H.sub.5                                872  "          "        3-CONH-n-C.sub.3 H.sub.7                             873  "          "        3-CONH-n-C.sub.4 H.sub.9                             874  "          "        3-CONH-n-C.sub.6 H.sub.13                            875  "          "        3-CONH-n-C.sub.10 H.sub.21                           876  "          "        3-CONH-i-C.sub.3 H.sub.7                             877  "          "        3-CON(CH.sub.3).sub.2                                878  "          "        3-CON(CH.sub.3)(nC.sub.6 H.sub.13)                   879  "          "        3-CON(C.sub.2 H.sub.5).sub.2                         880  "          "                                                                                      3 #STR92##                                           881  "          "                                                                                      4 #STR93##                                           882  "          "                                                                                      5 #STR94##                                           883  "          "                                                                                      6 #STR95##                                           884  "          "        3-CO--NH-c-C.sub.6 H.sub.11                          885  "          "        3-CO--NH-c-C.sub.3 H.sub.5                           886  "          "        3-CO--N(CH.sub.3)(cC.sub.6 H.sub.11)                 887  "          "        3-COSH                                               888  "          "        3-COSNa                                              889  "          "        3-COSCH.sub.3                                        890  "          "        3-COSC.sub.2 H.sub.5                                 891  "          "        3-COSCH.sub.2 C.sub.6 H.sub.5                        892  "          "        3-COS-nC.sub.8 H.sub.17                              893  "          "        3-COSC.sub.2 H.sub.4 OCH.sub.3                       894  "          "        3-COSCH.sub.2 CHCH.sub.2                             895  "          "        3-COSCH.sub.2 CCH                                    896  "          "        3-COS-c-C.sub.6 H.sub.11                             897  "          "        3-COSCH.sub.2 Si(CH.sub.3).sub.3                     898  "          "        3-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2           899  "          "                                                                                      7 #STR96##                                           900  "          "        3-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2              901  "          3-CH.sub.3                                                                             5-COOCH.sub.3                                        902  "          "        5-COOC.sub.2 H.sub.5   Oil                           903  "          "        5-COO-n-C.sub.3 H.sub.7                              904  "          "        5-COO-i-C.sub.3 H.sub.7                              905  "          "        5-COO-n-C.sub.4 H.sub.9                              906  "          "        5-COO-n-C.sub.5 H.sub.11                             907  "          "        5-COO-n-C.sub.6 H.sub.13                             908  "          "        5-COO-n-C.sub.8 H.sub.17                             909  "          "        5-COO-n-C.sub.10 H.sub.21                            910  "          "                                                                                      8 #STR97##                                           911  "          "        5-COOH                                               912  "          "        5-COOLi                                              913  "          "        5-COONa                                              914  "          "        5-COOK                                               915  "          "        5-COOCa.sub.1/2                                      916  "          "        5-COO-c-C.sub.4 H.sub.7                              917  "          "        5-COO-c-C.sub.6 H.sub.11                             918  "          "        5-COOCH.sub.2 --C.sub.6 H.sub.5                      919  "          "        5-COOCH.sub.2 -(2,4-Cl.sub.2 --C.sub.6 H.sub.3)      920  "          "        5-COO--CH.sub.2 CHCH.sub.2                           921  "          "        5-COO--C.sub.2 H.sub.4 CHCH.sub.2                    922  "          "        5-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                  923  "          "        5-COOCH.sub.2 CCH                                    924  "          "        5-COO-C.sub.2 H.sub.4 --CCH                          925  "          "        5-COO-n-C.sub.5 H.sub.10 CCH                         926  "          "        5-COOCH.sub.2 Si(CH.sub.3).sub.3                     927  "          "        5-COOC.sub.2 H.sub.4 OCH.sub.3                       928  "          "        5-CONH.sub.2                                         929  "          "        5-CN                                                 930  "          "        5-CONHCH.sub.3                                       931  3,5-Cl--CF.sub.3                                                                         "        5-CONHC.sub.2 H.sub.5                                932  "          "        5-CONH-n-C.sub.3 H.sub.7                             933  "          "        5-CONH-n-C.sub.4 H.sub.9                             934  "          "        5-CONH-n-C.sub.6 H.sub.13                            935  "          "        5-CONH-n-C.sub.10 H.sub.21                           936  "          "        5-CONH-i-C.sub.3 H.sub.7                             937  "          "        5-CON(CH.sub.3).sub.2                                938  "          "        5-CON(CH.sub.3)(nC.sub.6 H.sub.13)                   939  "          "        5-CON(C.sub.2 H.sub.5).sub.2                         940  "          "                                                                                      9 #STR98##                                           941  "          "                                                                                      0 #STR99##                                           942  "          "                                                                                      1 #STR100##                                          943  "          "                                                                                      2 #STR101##                                          944  "          "        5-CO--NH-c-C.sub.6 H.sub.11                          945  "          "        5-CO--NH-c-C.sub.3 H.sub.5                           946  "          "        5-CO--N(CH.sub.3)(cC.sub.6 H.sub.11)                 947  "          "        5-COSH                                               948  "          "        5-COSNa                                              949  "          "        5-COSCH.sub.3                                        950  "          "        5-COSC.sub.2 H.sub.5                                 951  "          "        5-COSCH.sub.2 C.sub.6 H.sub.5                        952  "          "        5-COS-nC.sub.8 H.sub.17                              953  "          "        5-COSC.sub.2 H.sub.4 OCH.sub.3                       954  "          "        5-COSCH.sub.2 CHCH.sub.2                             955  "          "        5-COSCH.sub.2 CCH                                    956  "          "        5-COS-c-C.sub.6 H.sub.11                             957  "          "        5-COSCH.sub.2 Si(CH.sub.3).sub.3                     958  "          "        5-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2           959  "          "                                                                                      3 #STR102##                                          960  "          "        5-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2              961  2,3-Cl.sub.2                                                                             5-CH.sub.3                                                                             3-COOCH.sub.3                                        962  "          "        3-COOC.sub.2 H.sub.5   77-79                         963  "          "        3-COO-n-C.sub.3 H.sub.7                              964  "          "        3-COO-i-C.sub.3 H.sub.7                              965  "          "        3-COO-n-C.sub.4 H.sub.9                              966  "          "        3-COO-n-C.sub.5 H.sub.11                             967  "          "        3-COO-n-C.sub.6 H.sub.13                             968  "          "        3-COO-n-C.sub.8 H.sub.17                             969  "          "        3-COO-n-C.sub.10 H.sub.21                            970  "          "                                                                                      2 #STR103##                                          971  "          "        3-COOH                                               972  "          "        3-COOLi                                              973  "          "        3-COONa                                              974  "          "        3-COOK                                               975  "          "        3-COOCa.sub.1/2                                      976  "          "        3-COO-c-C.sub.4 H.sub.7                              977  "          "        3-COO-c-C.sub.6 H.sub.11                             978  "          "        3-COOCH.sub.2 --C.sub.6 H.sub.5                      979  "          "        3-COOCH.sub.2 -(2,4-Cl.sub.2 --C.sub.6 H.sub.3)      980  "          "        3-COOCH.sub.2 CHCH.sub.2                             981  "          "        3-COOC.sub.2 H.sub.4 CHCH.sub.2                      982  "          "        3-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                  983  "          "        3-COO--CH.sub.2 CCH                                  984  "          "        3-COO--C.sub.2 H.sub.4 --CCH                         985  "          "        3-COO-n-C.sub.5 H.sub.10 CCH                         986  "          "        3-COOCH.sub.2 Si(CH.sub.3).sub.3                     987  "          "        3-COOC.sub.2 H.sub.4 OCH.sub.3                       988  "          "        3-CONH.sub.2                                         989  "          "        3-CN                                                 990  "          "        3-CONHCH.sub.3                                       991  "          "        3-CONHC.sub.2 H.sub.5                                992  "          "        3-CONH-n-C.sub.3 H.sub.7                             993  "          "        3-CONH-n-C.sub.4 H.sub.9                             994  "          "        3-CONH-n-C.sub.6 H.sub.13                            995  "          "        3-CONH-n-C.sub.10 H.sub.21                           996  "          "        3-CONH-i-C.sub.3 H.sub.7                             997  "          "        3-CON(CH.sub.3).sub.2                                998  "          "        3-CON(CH.sub.3)(nC.sub.6 H.sub.13)                   999  "          "        3-CON(C.sub.2 H.sub.5).sub.2                         1000 "          "                                                                                      3 #STR104##                                          1001 "          "                                                                                      4 #STR105##                                          1002 "          "                                                                                      5 #STR106##                                          1003 "          "                                                                                      6 #STR107##                                          1004 "          "        3-CO--NH-c-C.sub.6 H.sub.11                          1005 "          "        3-CO--NH-c-C.sub.3 H.sub.5                           1006 "          "        3-CO--N(CH.sub.3)(cC.sub.6 H.sub.11)                 1007 "          "        3-COSH                                               1008 "          "        3-COSNa                                              1009 "          "        3-COSCH.sub.3                                        1010 "          "        3-COSC.sub.2 H.sub.5                                 1011 "          "        3-COSCH.sub.2 C.sub.6 H.sub.5                        1012 "          "        3-COS-nC.sub.8 H.sub.17                              1013 "          "        3-COSC.sub.2 H.sub.4 OCH.sub.3                       1014 "          "        3-COSCH.sub.2 CHCH.sub.2                             1015 "          "        3-COSCH.sub.2 CCH                                    1016 "          "        3-COS-c-C.sub.6 H.sub.11                             1017 "          "        3-COSCH.sub.2 Si(CH.sub.3).sub.3                     1018 "          "        3-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2           1019 "          "                                                                                      7 #STR108##                                          1020 "          "        3-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2              1021 2,4,5-Cl.sub.2 OCH.sub.3                                                                 "        3-COOCH.sub.3                                        1022 "          "        3-COOC.sub.2 H.sub.5   155-159                       1023 "          "        3-COO-n-C.sub.3 H.sub.7                              1024 "          "        3-COO-i-C.sub.3 H.sub.7                              1025 "          "        3-COO-n-C.sub.4 H.sub.9                              1026 "          "        3-COO-n-C.sub.5 H.sub.11                             1027 "          "        3-COO-n-C.sub.6 H.sub.13                             1028 "          "        3-COO-n-C.sub.8 H.sub.17                             1029 "          "        3-COO-n-C.sub.10 H.sub.21                            1030 "          "                                                                                      2 #STR109##                                          1031 "          "        3-COOH                                               1032 "          "        3-COOLi                                              1033 "          "        3-COONa                                              1034 "          "        3-COOK                                               1035 "          "        3-COOCa.sub.1/2                                      1036 "          "        3-COO-c-C.sub.4 H.sub.7                              1037 "          "        3-COO-c-C.sub.6 H.sub.11                             1038 "          "        3-COOCH.sub.2 --C.sub.6 H.sub.5                      1039 "          "        3-COOCH.sub.2 -(2,4-Cl.sub.2 --C.sub.6 H.sub.3)      1040 "          "        3-COOCH.sub.2 CHCH.sub.2                             1041 "          "        3-COOC.sub.2 H.sub.4 CHCH.sub.2                      1042 "          "        3-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                  1043 "          "        3-COO--CH.sub.2 CCH                                  1044 "          "        3-COO--C.sub.2 H.sub.4 --CCH                         1045 "          "        3-COO-n-C.sub.5 H.sub.10 CCH                         1046 "          "        3-COOCH.sub.2 Si(CH.sub.3).sub.3                     1047 "          "        3-COOC.sub.2 H.sub.4 OCH.sub.3                       1048 "          "        3-CONH.sub.2                                         1049 "          "        3-CN                                                 1050 "          "        3-CONHCH.sub.3                                       1051 "          "        3-CONHC.sub.2 H.sub.5                                1052 "          "        3-CONH-n-C.sub.3 H.sub.7                             1053 "          "        3-CONH-n-C.sub.4 H.sub.9                             1054 "          "        3-CONH-n-C.sub.6 H.sub.13                            1055 "          "        3-CONH-n-C.sub.10 H.sub.21                           1056 "          "        3-CONH-i-C.sub.3 H.sub.7                             1057 "          "        3-CON(CH.sub.3).sub.2                                1058 "          "        3-CON(CH.sub.3)(nC.sub.6 H.sub.13)                   1059 "          "        3-CON(C.sub.2 H.sub.5).sub.2                         1060 "          "                                                                                      3 #STR110##                                          1061 "          "                                                                                      4 #STR111##                                          1062 "          "                                                                                      5 #STR112##                                          1063 "          "                                                                                      6 #STR113##                                          1064 "          "        3-CO--NH-c-C.sub.6 H.sub.11                          1065 "          "        3-CO--NH-c-C.sub.3 H.sub.5                           1066 "          "        3-CO--N(CH.sub.3)(cC.sub.6 H.sub.11)                 1067 "          "        3-COSH                                               1068 "          "        3-COSNa                                              1069 "          "        3-COSCH.sub.3                                        1070 "          "        3-COSC.sub.2 H.sub.5                                 1071 "          "        3-COSCH.sub.2 C.sub.6 H.sub.5                        1072 "          "        3-COS-nC.sub.8 H.sub.17                              1073 "          "        3-COSC.sub.2 H.sub.4 OCH.sub.3                       1074 "          "        3-COSCH.sub.2 CHCH.sub.2                             1075 "          "        3-COSCH.sub.2 CCH                                    1076 "          "        3-COS-c-C.sub.6 H.sub.11                             1077 "          "        3-COSCH.sub.2 Si(CH.sub.3).sub.3                     1078 "          "        3-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2           1079 "          "                                                                                      7 #STR114##                                          1080 "          "        3-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2              1081 "          3-CH.sub.3                                                                             5-COOCH.sub.3                                        1082 "          "        5-COOC.sub.2 H.sub.5   Oil                           1083 "          "        5-COO-n-C.sub.3 H.sub.7                              1084 "          "        5-COO-i-C.sub.3 H.sub.7                              1085 "          "        5-COO-n-C.sub.4 H.sub.9                              1086 "          "        5-COO-n-C.sub.5 H.sub.11                             1087 "          "        5-COO-n-C.sub.6 H.sub.13                             1088 "          "        5-COO-n-C.sub.8 H.sub.17                             1089 "          "        5-COO-n-C.sub.10 H.sub.21                            1090 "          "                                                                                      8 #STR115##                                          1091 "          "        5-COOH                                               1092 "          "        5-COOLi                                              1093 "          "        5-COONa                                              1094 "          "        5-COOK                                               1095 "          "        5-COOCa.sub.1/2                                      1096 "          "        5-COO-c-C.sub.4 H.sub.7                              1097 "          "        5-COO-c-C.sub.6 H.sub.11                             1098 "          "        5-COOCH.sub.2 --C.sub.6 H.sub.5                      1099 "          "        5-COOCH.sub.2 -(2,4-Cl.sub.2 --C.sub.6 H.sub.3)      1100 "          "        5-COOCH.sub.2 CHCH.sub.2                             1101 "          "        5-COOC.sub.2 H.sub.4 CHCH.sub.2                      1102 "          "        5-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                  1103 "          "        5-COO--CH.sub.2 CCH                                  1104 "          "        5-COO--C.sub.2 H.sub.4 --CCH                         1105 "          "        5-COO-n-C.sub.5 H.sub.10 CCH                         1106 "          "        5-COOCH.sub.2 Si(CH.sub.3).sub.3                     1107 "          "        5-COOC.sub.2 H.sub.4 OCH.sub.3                       1108 "          "        5-CONH.sub.2                                         1109 "          "        5-CN                                                 1110 "          "        5-CONHCH.sub.3                                       1111 "          "        5-CONHC.sub.2 H.sub.5                                1112 "          "        5-CONH-n-C.sub.3 H.sub.7                             1113 "          "        5-CONH-n-C.sub.4 H.sub.9                             1114 "          "        5-CONH-n-C.sub.6 H.sub.13                            1115 "          "        5-CONH-n-C.sub.10 H.sub.21                           1116 "          "        5-CONH-i-C.sub.3 H.sub.7                             1117 "          "        5-CON(CH.sub.3).sub.2                                1118 "          "        5-CON(CH.sub.3)(nC.sub.6 H.sub.13)                   1119 "          "        5-CON(C.sub.2 H.sub.5).sub.2                         1120 "          "                                                                                      9 #STR116##                                          1121 "          "                                                                                      0 #STR117##                                          1122 "          "                                                                                      1 #STR118##                                          1123 "          "                                                                                      2 #STR119##                                          1124 "          "        5-CO--NH-c-C.sub.6 H.sub.11                          1125 "          "        5-CO--NH-c-C.sub.3 H.sub.5                           1126 "          "        5-CO--N(CH.sub.3)(cC.sub.6 H.sub.11)                 1127 "          "        5-COSH                                               1128 "          "        5-COSNa                                              1129 "          "        5-COSCH.sub.3                                        1130 "          "        5-COSC.sub.2 H.sub.5                                 1131 "          "        5-COSCH.sub.2 C.sub.6 H.sub.5                        1132 "          "        5-COS-nC.sub.8 H.sub.17                              1133 "          "        5-COSC.sub.2 H.sub.4 OCH.sub.3                       1134 "          "        5-COSCH.sub.2 CHCH.sub.2                             1135 "          "        5-COSCH.sub.2 CCH                                    1136 "          "        5-COS-c-C.sub.6 H.sub.11                             1137 "          "        5-COSCH.sub.2 Si(CH.sub.3).sub.3                     1138 "          "        5-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2           1139 "          "                                                                                      3 #STR120##                                          1140 "          "        5-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2              1141 2,6,3-(C.sub.2 H.sub.5).sub.2 Cl                                                         5-CH.sub.3                                                                             3-COOCH.sub.3                                        1142 "          "        3-COOC.sub.2 H.sub.5   Oil                           1143 "          "        3-COO-n-C.sub.3 H.sub.7                              1144 "          "        3-COO-i-C.sub.3 H.sub.7                              1145 "          "        3-COO-n-C.sub.4 H.sub.9                              1146 "          "        3-COO-n-C.sub.5 H.sub.11                             1147 "          "        3-COO-n-C.sub.6 H.sub.13                             1148 "          "        3-COO-n-C.sub.8 H.sub.17                             1149 "          "        3-COO-n-C.sub.10 H.sub.21                            1150 "          "                                                                                      2 #STR121##                                          1151 "          "        3-COOH                                               1152 "          "        3-COOLi                                              1153 "          "        3-COONa                                              1154 "          "        3-COOK                                               1155 "          "        3-COOCa.sub.1/2                                      1156 "          "        3-COO-c-C.sub.4 H.sub.7                              1157 "          "        3-COO-c-C.sub.6 H.sub.11                             1158 "          "        3-COOCH.sub.2 --C.sub.6 H.sub.5                      1159 "          "        3-COOCH.sub.2 -(2,4-Cl.sub.2 --C.sub.6 H.sub.3)      1160 "          "        3-COOCH.sub.2 CHCH.sub.2                             1161 "          "        3-COOC.sub.2 H.sub.4 CHCH.sub.2                      1162 "          "        3-COO-n-C.sub.8 H.sub.16 CHCH.sub.2                  1163 "          "        3-COO--CH.sub.2 CCH                                  1164 "          "        3-COO--C.sub.2 H.sub.4 --CCH                         1165 "          "        3-COO-n-C.sub.5 H.sub.10 CCH                         1166 "          "        3-COOCH.sub.2 Si(CH.sub.3).sub.3                     1167 "          "        3-COOC.sub.2 H.sub.4 OCH.sub.3                       1168 "          "        3-CONH.sub.2                                         1169 "          "        3-CN                                                 1170 "          "        3-CONHCH.sub.3                                       1171 "          "        3-CONHC.sub.2 H.sub.5                                1172 "          "        3-CONH-n-C.sub.3 H.sub.7                             1173 "          "        3-CONH-n-C.sub.4 H.sub.9                             1174 "          "        3-CONH-n-C.sub.6 H.sub.13                            1175 "          "        3-CONH-n-C.sub.10 H.sub.21                           1176 "          "        3-CONH-i-C.sub.3 H.sub.7                             1177 "          "        3-CON(CH.sub.3).sub.2                                1178 "          "        3-CON(CH.sub.3)(nC.sub.6 H.sub.13)                   1179 "          "        3-CON(C.sub.2 H.sub.5).sub.2                         1180 "          "                                                                                      3 #STR122##                                          1181 "          "                                                                                      4 #STR123##                                          1182 "          "                                                                                      5 #STR124##                                          1183 "          "                                                                                      6 #STR125##                                          1184 "          "        3-CO--NH-c-C.sub.6 H.sub.11                          1185 "          "        3-CO--NH-c-C.sub.3 H.sub.5                           1186 "          "        3-CO--N(CH.sub.3)(cC.sub.6 H.sub.11)                 1187 "          "        3-COSH                                               1188 "          "        3-COSNa                                              1189 "          "        3-COSCH.sub.3                                        1190 "          "        3-COSC.sub.2 H.sub.5                                 1191 "          "        3-COSCH.sub.2 C.sub.6 H.sub.5                        1192 "          "        3-COS-nC.sub.8 H.sub.17                              1193 "          "        3-COSC.sub.2 H.sub.4 OCH.sub.3                       1194 "          "        3-COSCH.sub.2 CHCH.sub.2                             1195 "          "        3-COSCH.sub.2 CCH                                    1196 "          "        3-COS-c-C.sub.6 H.sub.11                             1197 "          "        3-COSCH.sub.2 Si(CH.sub.3).sub.3                     1198 "          "        3-COS-n-C.sub.4 H.sub.8 CH(CH.sub.3).sub.2           1199 "          "                                                                                      7 #STR126##                                          1200 "          "        3-COOC.sub.2 H.sub.4 CH(CH.sub.3).sub.2              1201 3-CF.sub.3 3-CH.sub.3                                                                             5-COOH                 164-170                       1202 3,2,6-Cl(C.sub.2 H.sub.5).sub.2                                                          "        5-COOC.sub.2 H.sub.5   Oil                           1203 4,2-Cl--CF.sub.3 --Phe                                                                   3-CH.sub.5                                                                             5-COOC.sub.2 H.sub.5   Oil                           1204 3-CF.sub.3 5-C(CH.sub.3).sub.3                                                                    3-COOC.sub.2 H.sub.5   Oil                           1205 2,4-Br.sub.2                                                                             5-C(CH.sub.3).sub.3                                                                    3-COOC.sub.2 H.sub.5   130-132                       1206 2,3-Cl.sub.2                                                                             5-C(CH.sub.3).sub.3                                                                    3-COOC.sub.2 H.sub.5   101-102                       1207 2,6,4-Cl.sub.2 --CF.sub.3                                                                3-CH.sub.2 CH(CH.sub.3).sub.2                                                          5-COOC.sub.2 H.sub.5   Oil                           1208 "          5-CH.sub.2 CH(CH.sub.3).sub.2                                                          3-COOC.sub.2 H.sub.5   82-84                         1209 2,4-Cl.sub.2                                                                             3-CH.sub.2 CH(CH.sub.3).sub.2                                                          5-COOC.sub.2 H.sub.5   Oil                           1210 2,4-Br.sub.2                                                                             3-i-C.sub.3 H.sub.7                                                                    5-COOC.sub.2 H.sub.5                                 1211 3-CF.sub.3 5-CH.sub.2 CH(CH.sub.3).sub.2                                                          3-COOC.sub.2 H.sub.5   Oil                           1212 2,6,4-Cl.sub.2 --CF.sub.3                                                                5-CH.sub.2 CH(CH.sub.3).sub.2                                                          3-COOH                 191-193                       1213 2,3-Cl.sub.2 --Phe                                                                       5-CH     3-COOC.sub.2 H.sub.5   76-78                         1214 "          5-CH.sub.2 CH(CH.sub.3)                                                                3-COOC.sub.2 H.sub.5   91-92                         1215 2,4-Br.sub.2                                                                             5-CH.sub.2 CH(CH.sub.3)                                                                3-COOEt                Oil                           1216 2,4-Cl.sub.2                                                                             5-CH.sub.3                                                                             3-COOCH.sub.2 CH(CH.sub.3)CH.sub.2 CH.sub.3                                                          39-45                         1217 3-CF.sub.3 5-CH.sub.3                                                                             3-COOC.sub.2 H.sub.5   Oil                           1218 2,4-Br.sub.2                                                                             5-CH(CH.sub.3).sub.2                                                                   3-COOC.sub.2 H.sub.5   72-79                         1219 2,4-Cl--CF.sub.3                                                                         3-CH(CH.sub.3).sub.2                                                                   5-COOC.sub.2 H.sub.5   Oil                           1220 "          5-CH(CH.sub.3).sub.2                                                                   3-COOC.sub.2 H.sub.5   58-70                         1221 2,4-Br.sub.2                                                                             5-CH.sub.2 CH(CH.sub.3).sub.2                                                          3-COOC.sub.2 H.sub.5   184-187                       1222 2,4-Cl--CF.sub.3                                                                         5-C(CH.sub.3).sub.3                                                                    3-COOC.sub.2 H.sub.5   106-107                       1223 2,6,4-Cl.sub.2 --CF.sub.3                                                                5-CH.sub.2 CH(CH.sub.3).sub.2                                                          3-COO.sup.- Li.sup.+   >250                          1224 2,3-Cl.sub.2                                                                             5-CH.sub.2 CH(CH.sub.3).sub.2                                                          3-COOH                 209-211                       1225 2,4-Cl--CF.sub.3                                                                         5-CH.sub.2 CH(CH.sub.3).sub.2                                                          3-COOC.sub.2 H.sub.5   54-58                         1226 2,4,5-Cl, F--CH.sub.3 --Phe                                                              5-CH.sub.3                                                                             3-COOC.sub.2 H.sub.5   109-110                       1227 3,4-Cl, --CH.sub.3 --Phe                                                                 5-CH.sub.3                                                                             3-COOC.sub.2 H.sub.5   77-80                         1228 2,4-Cl.sub.2 --Phe                                                                       5-CH.sub.3                                                                             3-COOHN(C.sub.2 H.sub.4 OH).sub.3                                                                    135-138                       1229 2,4-Cl.sub.2 --Phe                                                                       5-CH.sub.3                                                                             3-CONHC(CH.sub.3)(CH(CH.sub.3).sub.2)CONH.sub.2                                                      65-69                         1230 2,4-Cl.sub.2 --Phe                                                                       5-CH.sub.3                                                                             3-C(NH.sub.2)NOH       205                           1231 2,6-(CH.sub.3).sub.2                                                                     5-CH.sub.3                                                                             3-COOC.sub.2 H.sub.5   Oil                           1232 4-F--Phe   5-CH.sub.3                                                                             3-COOC.sub.2 H.sub.5   Resin                         1233 4-OCH.sub.3 --Phe                                                                        5-CH.sub.3                                                                             3-COOC.sub.2 H.sub.5   Oil                           1234 2,4-Cl, CF.sub.3 --Phe                                                                   3-CH.sub.3                                                                             5-COOC.sub.2 H.sub.5   Oil                           1235 2,4-Cl.sub.2                                                                             5-c-C.sub.3 H.sub.5                                                                    3-COOC.sub.2 H.sub.5    80                           1236 2,6,4-Cl.sub.2, CF.sub.3 --Phe                                                           5-c-C.sub.3 H.sub.5                                                                    3-COOC.sub.2 H.sub.5   105-110                       __________________________________________________________________________     Abbreviations:                                                                n: straightchain                                                              i: iso (branched)                                                             c: cyclo                                                                 

C. BIOLOGICAL EXAMPLES Example 1

Wheat and barley were grown to the 3- to 4-leaf stage in plastic pots ina greenhouse and were then treated in succession by the post-emergencemethod with the safener compounds and the herbicides tested. Theherbicides and the compounds of the formula I were applied here in theform of aqueous suspensions or emulsions with a water applicationamount, when converted, of 800 l/ha. 3 to 4 weeks after the treatment,the plants were rated visually for any type of damage by the herbicidesapplied, the extent of the persistent inhibition of growth being takeninto particular account. The degree of damage or the safener action of Iwas determined in % damage.

The results From Table I illustrate that the compounds according to theinvention can effectively reduce severe herbicide damage to the cropplants.

Even in cases of high overdoses of the herbicide, severe damageoccurring to the crop plants is significantly reduced, and milder damageis eliminated completely. Mixtures of herbicides and compounds accordingto the invention are therefore advantageously suitable for selectivelycombating weeds in cereal crops.

                  TABLE 1                                                         ______________________________________                                        Safener action of the compounds according to the invention                                              % damage                                            Combination Dosage        (safener action)                                    Herbicide/Safener                                                                         (kg of a.s./ha)                                                                             TA      HV                                          ______________________________________                                        H.sub.1     2.0           80      --                                                      0.2           --      85                                          H.sub.1 + 122                                                                             2.0 ± 2.5  10      --                                                      0.2 ± 2.5  --      20                                          H.sub.1 + 148                                                                             2.0 ± 2.5  50      --                                                      0.2 ± 2.5  --      40                                          H.sub.1 + 182                                                                             2.0 ± 2.5  40      --                                                      0.2 ± 2.5  --      35                                          H.sub.1 + 542                                                                             2.0 ± 2.5  30      --                                                      0.2 ± 2.5  --      35                                          H.sub.1 + 131                                                                             2.0 ± 2.5  20      --                                                      0.2 ± 2.5  --      40                                          H.sub.1 + 191                                                                             2.0 ± 2.5  20      --                                                      0.2 ± 2.5  --      45                                          H.sub.1 + 1 2.0 ± 2.5  15      --                                                      0.2 ± 2.5  --      45                                          H.sub.1 + 782                                                                             2.0 ± 2.5  20      --                                                      0.2 ± 2.5  --      40                                          H.sub.1 + 602                                                                             2.0 ± 2.5  20      --                                                      0.2 ± 2.5  --      50                                          H.sub.1 + 1201                                                                            2.0 ± 2.5  35      --                                                      0.2 ± 2.5  --      50                                          H.sub.1 + 611                                                                             2.0 ± 2.5  35      --                                                      0.2 ± 2.5  --      50                                          H.sub.1 + 1202                                                                            2.0 ± 2.5  50      --                                                      0.2 ± 2.5  --      70                                          H.sub.1 + 1142                                                                            2.0 ± 2.5  25      --                                                      0.2 ± 2.5  --      40                                          H.sub.1 + 842                                                                             2.0 ± 2.5  25      --                                                      0.2 ± 2.5  --      30                                          H.sub.1 + 902                                                                             2.0 ± 2.5  50      --                                                      0.2 ± 2.5  --      55                                          H.sub.1 + 71                                                                              2.0 ± 2.5  50      --                                                      0.2 ± 2.5  --      65                                          H.sub.1 + 632                                                                             2.0 ± 2.5  30      --                                                      0.2 ± 2.5  --      85                                          H.sub.1 + 605                                                                             2.0 ± 2.5  70      --                                                      0.2 ± 2.5  --      40                                          H.sub.1 + 722                                                                             2.0 ± 2.5  20      --                                                      0.2 ± 2.5  --      50                                          H.sub.1 + 152                                                                             2.0 ± 2.5  40      --                                                      0.2 ± 2.5  --      85                                          H.sub.1 + 212                                                                             2.0 ± 2.5  40      --                                                      0.2 ± 2.5  --      70                                          H.sub.1 + 302                                                                             2.0 ± 2.5  60      --                                                      0.2 ± 2.5  --      30                                          H.sub.1 + 362                                                                             2.0 ± 2.5  20      --                                                      0.2 ± 2.5  --      20                                          H.sub.1 + 1204                                                                            2.0 ± 2.5  60      --                                                      0.2 ± 2.5  --      50                                          H.sub.1 + 1205                                                                            2.0 ± 2.5  60      --                                                      0.2 ± 2.5  --      50                                          H.sub.1 + 1206                                                                            2.0 ± 2.5  60      --                                                      0.2 ± 2.5  --      50                                          H.sub.1 + 1207                                                                            2.0 ± 2.5  55      --                                                      0.2 ± 2.5  --      45                                          H.sub.1 + 1208                                                                            2.0 ± 2.5  60      --                                                      0.2 ± 2.5  --      45                                          H.sub.1 + 1209                                                                            2.0 ± 2.5  70      --                                                      0.2 ± 2.5  --      45                                          H.sub.1 + 422                                                                             2.0 ± 2.5  70      --                                                      0.2 ± 2.5  --      50                                          H.sub.1 + 1210                                                                            2.0 ± 2.5  70      --                                                      0.2 ± 2.5  --      55                                          H.sub.1 + 1211                                                                            2.0 ± 2.5  60      --                                                      0.2 ± 2.5  --      50                                          H.sub.1 + 1212                                                                            2.0 ± 2.5  70      --                                                      0.2 ± 2.5  --      40                                          H.sub.1 + 1213                                                                            2.0 ± 2.5  40      --                                                      0.2 ± 2.5  --      30                                          H.sub.1 + 1214                                                                            2.0 ± 2.5  60      --                                                      0.2 ± 2.5  --      10                                          H.sub.1 + 121                                                                             2.0 ± 2.5  25      --                                                      0.2 ± 2.5  --      40                                          H.sub.1 + 123                                                                             "             60      --                                                      "             --      40                                          H.sub.1 + 124                                                                              2.0 ± 1.25                                                                              20      --                                                       0.2 ± 1.25                                                                              --      30                                          H.sub.1 + 125                                                                             2.0 ± 2.5  60      --                                                      0.2 ± 2.5  --      40                                          H.sub.1 + 127                                                                             "             40      --                                                      "             --      30                                          H.sub.1 + 128                                                                              2.0 ± 1.25                                                                              20      --                                                       0.2 ± 1.25                                                                              --      40                                          H.sub.1 + 132                                                                             2.0 ± 2.5  30      --                                                      0.2 ± 2.5  --      30                                          H.sub.1 + 133                                                                              2.0 ± 1.25                                                                              20      --                                                       0.2 ± 1.25                                                                              --      30                                          H.sub.1 + 135                                                                             2.0 ± 2.5  30      --                                                      0.2 ± 2.5  --      30                                          H.sub.1 + 137                                                                              2.0 ± 1.25                                                                              40      --                                                       0.2 ± 1.25                                                                              --      50                                          H.sub.1 + 146                                                                              2.0 ± 1.25                                                                              40      --                                                       0.2 ± 1.25                                                                              --      70                                          H.sub.1 + 147                                                                             "             20      --                                                      "             --      20                                          H.sub.1 + 149                                                                             "             35      --                                                      "             --      40                                          H.sub.1 + 150                                                                             "             30      --                                                      "             --      80                                          H.sub.1 + 153                                                                             "             10      --                                                      "             --      30                                          H.sub.1 + 157                                                                             "             50      --                                                      "             --      75                                          H.sub.1 + 159                                                                             "             20      --                                                      "             --      20                                          H.sub.1 + 160                                                                             "             50      --                                                      "             --      60                                          H.sub.1 + 162                                                                             "             30      --                                                      "             --      80                                          H.sub.1 + 164                                                                             "             10      --                                                      "             --      70                                          H.sub.1 + 171                                                                             "             20      --                                                      "             --      75                                          H.sub.1 + 242                                                                             "             20      --                                                      "             --      30                                          H.sub.1 + 251                                                                             "             20      --                                                      "             --      20                                          H.sub.1 + 301                                                                             "             20      --                                                      "             --      30                                          H.sub.1 + 303                                                                             "             10      --                                                      "             --      20                                          H.sub.1 + 311                                                                             "             30      --                                                      "             --      30                                          H.sub.1 + 361                                                                              2.0 ± 1.25                                                                              15      --                                                       0.2 ± 1.25                                                                              --      20                                          H.sub.1 + 391                                                                             "             25      --                                                      "             --      50                                          H.sub.1 + 392                                                                             "             20      --                                                      "             --      70                                          H.sub.1 + 482                                                                             "             20      --                                                      "             --      40                                          H.sub.1 + 491                                                                             "             20      --                                                      "             --      40                                          H.sub.1 + 511                                                                             "             30      --                                                      "             --      85                                          H.sub.1 + 692                                                                             "             30      --                                                      "             --      40                                          H.sub.1 + 1022                                                                            "             30      --                                                      "             --      70                                          H.sub.1 + 1218                                                                            2.0 ± 2.5  30      --                                                      0.2 ± 2.5  --      20                                          H.sub.1 + 1219                                                                            "             35      --                                                      "             --      50                                          H.sub.1 + 1220                                                                            "             30      --                                                      "             --      20                                          H.sub.1 + 1221                                                                            "             30      --                                                      "             --      20                                          H.sub.1 + 1222                                                                            "             15      --                                                      "             --      30                                          H.sub.1 + 1223                                                                            "             20      --                                                      "             --      60                                          H.sub.1 + 1224                                                                            "             20      --                                                      "             --      60                                          H.sub.1 + 1225                                                                            "             50      --                                                      "             --      30                                          H.sub.1 + 1226                                                                             2.0 ± 1.25                                                                              30      --                                                       0.2 ± 1.25                                                                              --      70                                          H.sub.1 + 1227                                                                            "             50      --                                                      "             --      80                                          H.sub.1 + 1228                                                                            "             40      --                                                      "             --      70                                          H.sub.1 + 1229                                                                            "             30      --                                                      "             --      60                                          H.sub.1 + 1230                                                                            "             50      --                                                      "             --      80                                          H.sub.1 + 1231                                                                            "             40      --                                                      "             --      75                                          H.sub.1 + 1233                                                                            "             40      --                                                      "             --      75                                          H.sub.1 + 1235                                                                            "             20      --                                                      "             --      40                                          H.sub.1 + 1236                                                                            "             20      --                                                      "             --      60                                          ______________________________________                                         Abbreviations:                                                                TA = Triticum aestivum (wheat)                                                HV = Hordeum vulgare (barley)                                                 a.s. = active substance                                                       H.sub.1 = fenoxapropethyl                                                

We claim:
 1. A compound of the formula (I) ##STR127## in which Y is CH,R₁, if n=1, or each of the symbols R₁ independently of one another ifn=2 or 3, is (C₁ -C₄)-alkyl, (C₁ -C₄)-haloalkyl, (C₁ -C₄)-alkoxy, (C₁-C₄)-haloalkoxy or halogen,R₂ is a radical in the 5-position of thepyrazole ring and selected from (C₁ -C₁₂)-alkyl or (C₃ -C₇)-cycloalkyl,X is a radical of the formula COOR₃ in the 3-position of the pyrazolering, R₃ is an alkali metal or alkaline earth metal, hydrogen, (C₁-C₁₀)-alkyl, (C₃ -C₂₀)-alkenyl, (C₃ -C₁₀)-alkynyl, phenyl-(C₁-C₄)-alkyl, phenyl-(C₁ -C₄)-alkyl substituted in the phenyl ring byhalogen, tris- (C₁ -C₄)-alkyl!-silyl-(C₁ -C₄)-alkyl or (C₁-C₄)-alkoxy-(C₁ -C₄)-alkyl, n is 1, 2 or 3, provided that (i) R₃ is notH when n is 1, R₁ is 3-CF₃ and R₂ is 5-isobutyl, and (ii) R₃ is notethyl when n is 1, R₁ is 3-CF₃ and R₂ is 5-isobutyl.
 2. A compound asclaimed in claim 1, wherein R₁, if n=1, or each of the symbols R₁independently of one another if n=2 or 3, is (C₁ -C₄)-alkyl, (C₁-C₄)-haloalkyl or halogen,R₂ is (C₁ -C₆)-alkyl or cyclohexyl, R₃ is H or(C₁ -C₆)-alkyl.
 3. A compound as claimed in claim 1, wherein R₁ if n=1,or each of the symbols R₁ independently of one another if n=2, is (C₁-C₄)-haloalkyl or halogen,R₂ is (C₁ -C₆)-alkyl, R₃ is H or (C₁-C₆)-alkyl, n is 1 or
 2. 4. A compound as claimed in claim 1, whereineach of the symbols R₁ independently of one another, is Cl, Br or CF₃,R₂is (C₁ -C₆)-alkyl, R₃ is (C₁ -C₄)-alkyl, n is
 2. 5. A compound asclaimed in claim 4, wherein (R₁)_(n) is 2,4-Cl₂ ; R₂ is isopropyl; R₃ isethyl.
 6. A compound as claimed in claim 4, wherein (R₁)_(n) is 2,4-Cl₂; R₂ is isopropyl; R₃ is methyl.
 7. A compound as claimed in claim 4,wherein (R₁)_(n) is 2,4-Cl₂ ; R₂ is methyl; R₃ is ethyl.
 8. A compoundas claimed in claim 4, wherein (R₁)_(n) is 2,4-Cl₂ ; R₂ is ethyl; R₃ isethyl.
 9. A compound as claimed in claim 2, wherein (R₁)_(n) is 2,4-Cl₂; R₂ is cyclohexyl; R₃ is ethyl.
 10. A compound as claimed in claim 4,wherein (R₁)_(n) is 2,4-Cl₂ ; R₂ is tert.-butyl; R₃ is ethyl.
 11. Acompound as claimed in claim 4, wherein (R₁)_(n) is 2,4-Cl₂ ; R₂ is2-methyl-prop-1-yl; R₃ is ethyl.
 12. A compound as claimed in claim 4,wherein (R₁)_(n) is 2,4-Br₂ ; R₂ is isopropyl; R₃ is ethyl.
 13. Acompound as claimed in claim 4, wherein (R₁)_(n) is 4-CF₃, 2-Cl; R₂ isisopropyl; R₃ is ethyl.
 14. A compound as claimed in claim 4, wherein(R₁)_(n) is 4-CF₃, R₂ is tert.-butyl; R₃ is ethyl.
 15. A compound asclaimed in claim 4, wherein (R₁)_(n) is 4-CF₃, 2-Cl; R₂ is2-methyl-prop-1-yl; R₃ is ethyl.
 16. A compound as claimed in claim 4,wherein (R₁)_(n) is 2CF₃, 4-Cl; R₂ is 2-methyl-prop-1-yl; R₃ is ethyl.17. A compound as claimed in claim 3, wherein (R₁)_(n) is 3-CF₃ ; R₂ ismethyl; R₃ is n-butyl.
 18. A compound as claimed in claim 2, wherein(R₁)_(n) is 3 -Cl,2,6-Et₂ ; R₂ is methyl; R₃ is n-butyl.